Phosphotungstic Acid Encapsulated in Metal-Organic Framework as Catalysts for Carbohydrate Dehydration to 5-Hydroxymethylfurfural
文献类型：期刊论文
| 作者 | Zhang, Yanmei1,2; Degirmenci, Volkan2; Li, Can1; Hensen, Emiel J. M.2 |
| 刊名 | chemsuschem
 |
| 出版日期 | 2011 |
| 卷号 | 4期号:1页码:59-64 |
| ISSN号 | 待补充 |
| 关键词 | biomass carbohydrates heterogeneous catalysis metal-organic frameworks solid acids |
| 通讯作者 | 李灿 ; emielj.m.hensen |
| 产权排序 | 1,1 |
| 中文摘要 | phosphotungstic acid encapsulated in metal-organic framework as catalysts for carbohydrate dehydration to 5-hydroxymethylfurfural |
| 英文摘要 | mil-101, a chromium-based metal-organic framework, is known for its very large pore size, large surface area and good stability. however, applications of this material in catalysis are still limited. 5-hydroxymethylfurfural (hmf) has been considered a renewable chemical platform for the production of liquid fuels and fine chemicals. phosphotungstic acid, h(3)pw(12)o(40) (pta), encapsulated in mil-101 is evaluated as a potential catalyst for the selective dehydration of fructose and glucose to 5-hydroxymethylfurfural. the results demonstrate that pta/mil-101 is effective for hmf production from fructose in dmso and can be reused. this is the first example of the application of a metal-organic framework in carbohydrate dehydration. |
| 学科主题 | 物理化学 |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | mesoporous silica ; hydrogen storage ; drug-delivery ; surface-area ; ionic liquid ; giant pores ; d-fructose ; biomass ; sites ; oxidation |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000287138900010 |
| 公开日期 | 2012-07-09 |
| 源URL | [http://159.226.238.44/handle/321008/115742]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Eindhoven Univ Technol, Schuit Inst Catalysis, NL-5600 MB Eindhoven, Netherlands |
| 推荐引用方式 GB/T 7714 | Zhang, Yanmei,Degirmenci, Volkan,Li, Can,et al. Phosphotungstic Acid Encapsulated in Metal-Organic Framework as Catalysts for Carbohydrate Dehydration to 5-Hydroxymethylfurfural[J]. chemsuschem,2011,4(1):59-64. |
| APA | Zhang, Yanmei,Degirmenci, Volkan,Li, Can,&Hensen, Emiel J. M..(2011).Phosphotungstic Acid Encapsulated in Metal-Organic Framework as Catalysts for Carbohydrate Dehydration to 5-Hydroxymethylfurfural.chemsuschem,4(1),59-64. |
| MLA | Zhang, Yanmei,et al."Phosphotungstic Acid Encapsulated in Metal-Organic Framework as Catalysts for Carbohydrate Dehydration to 5-Hydroxymethylfurfural".chemsuschem 4.1(2011):59-64. |
入库方式： OAI收割
来源：大连化学物理研究所
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