Synthesize, crystal structure, heat capacities and thermodynamic properties of a potential enantioselective catalyst
文献类型：期刊论文
| 作者 | Zeng, Ju-Lan1; Yu, Sai-Bo2; Cao, Zhong1; Yang, Dao-Wu1; Sun, Li-Xian3; Zhang, Ling1; Zhang, Xiong-Fei1 |
| 刊名 | journal of thermal analysis and calorimetry
 |
| 出版日期 | 2011-09-01 |
| 卷号 | 105期号:3页码:961-968 |
| 关键词 | Enantioselective catalyst Crystal structure Molar heat capacity Thermodynamic functions |
| ISSN号 | 1388-6150 |
| 产权排序 | 3,5 |
| 通讯作者 | zengjulan ; yusai-bo |
| 中文摘要 | synthesize, crystal structure, heat capacities and thermodynamic properties of a potential enantioselective catalyst |
| 英文摘要 | a new potential enantioselective catalyst derived from ferrocene, 1-{(r)-1-[(s)-2-(diphenylphosphino)ferrocenyl]ethyl}-benzimidazole (dpfeb), was prepared and its absolute structure was characterized by means of single crystal x-ray diffraction. the molar heat capacity of dpfeb was measured by means of temperature modulated differential scanning calorimetry over the temperature range of 200-530 k, and the thermodynamic functions of [h (t) - h (298.15)] and [s (t) - s (298.15)] were calculated. further more, thermogravimetry experiment revealed that dpfeb exhibited a three step thermal decomposition process with the final residual of 28.7%. |
| WOS标题词 | science & technology ; physical sciences |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, analytical ; chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | ferrocene derivatives ; chiral ferrocenylphosphines ; asymmetric-synthesis ; ligands ; polymers |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000294014000026 |
| 公开日期 | 2012-07-09 |
| 源URL | [http://159.226.238.44/handle/321008/115758]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Changsha Univ Sci & Technol, Hunan Prov Key Lab Mat Protect Elect Power & Tran, Sch Chem & Biol Engn, Changsha 410004, Hunan, Peoples R China 2.China Tobacco Hunan Ind Corp, Changsha 410007, Hunan, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zeng, Ju-Lan,Yu, Sai-Bo,Cao, Zhong,et al. Synthesize, crystal structure, heat capacities and thermodynamic properties of a potential enantioselective catalyst[J]. journal of thermal analysis and calorimetry,2011,105(3):961-968. |
| APA | Zeng, Ju-Lan.,Yu, Sai-Bo.,Cao, Zhong.,Yang, Dao-Wu.,Sun, Li-Xian.,...&Zhang, Xiong-Fei.(2011).Synthesize, crystal structure, heat capacities and thermodynamic properties of a potential enantioselective catalyst.journal of thermal analysis and calorimetry,105(3),961-968. |
| MLA | Zeng, Ju-Lan,et al."Synthesize, crystal structure, heat capacities and thermodynamic properties of a potential enantioselective catalyst".journal of thermal analysis and calorimetry 105.3(2011):961-968. |
入库方式： OAI收割
来源：大连化学物理研究所
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