Oxidative Desulfurization of Fuel Oils
文献类型：期刊论文
| 作者 | Jiang Zongxuan; Lue Hongying; Zhang Yongna; Li Can |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2011-05-01 |
| 卷号 | 32期号:5页码:707-715 |
| 关键词 | oxidative desulfurization emulsion catalysis extraction fuel oil |
| ISSN号 | 待补充 |
| 产权排序 | 1,1 |
| 通讯作者 | 李灿 |
| 中文摘要 | oxidative desulfurization of fuel oils |
| 英文摘要 | several attractive approaches toward oxidative desulfurization of fuel oils, such as using h(2)o(2)/organic acids, h(2)o(2)/heteropolyacid, h(2)o(2)/ti-containing zeolites, and other non-hydrogen peroxide systems (e.g., t-butyl hydroperoxide etc.) are reviewed. a new alternative oxidative desulfurization process using emulsion catalysts was developed mainly by our group, is introduced in detail. limitations because of interphase mass transfer are greatly reduced in the emulsion reaction medium. the amphiphilic emulsion catalysts can selectively oxidize the sulfur-containing molecules present in diesel to their corresponding sulfones when using h(2)o(2) as the oxidant under mild conditions. tie sulfones in the oxidized fuel oils can be removed by a polar extractant. the sulfur level of a prehydrotreated diesel can be lowered from a few hundred mu g/g to 0.1 mu g/g after oxidation and subsequent extraction whereas the sulfur level of a straight-run diesel can be decreased from 6000 to 30 mu g/g after oxidation and extraction. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | ultra-deep desulfurization ; tert-butyl hydroperoxide ; liquid-phase oxidation ; light gas oil ; diesel fuel ; hydrogen-peroxide ; sulfur-compounds ; emulsion droplets ; selective oxidation ; titanosilicate precursors |
| 收录类别 | SCI ; ISTP |
| 语种 | 英语 |
| WOS记录号 | WOS:000291508200002 |
| 公开日期 | 2012-07-09 |
| 源URL | [http://159.226.238.44/handle/321008/115760]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang Zongxuan,Lue Hongying,Zhang Yongna,et al. Oxidative Desulfurization of Fuel Oils[J]. chinese journal of catalysis,2011,32(5):707-715. |
| APA | Jiang Zongxuan,Lue Hongying,Zhang Yongna,&Li Can.(2011).Oxidative Desulfurization of Fuel Oils.chinese journal of catalysis,32(5),707-715. |
| MLA | Jiang Zongxuan,et al."Oxidative Desulfurization of Fuel Oils".chinese journal of catalysis 32.5(2011):707-715. |
入库方式： OAI收割
来源：大连化学物理研究所
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