Ultra-deep Oxidative Desulfurization of Fuel Oil Catalyzed by Dawson-Type Polyoxotungstate Emulsion Catalysts
文献类型：期刊论文
| 作者 | Zhang Yongna1,2; Wang Lu1,2; Zhang Yuliang1,2; Jiang Zongxuan1; Li Can1 |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2011-02-01 |
| 卷号 | 32期号:2页码:235-239 |
| 关键词 | Dawson-type polyoxotungstate emulsion catalyst oxidative desulfurization |
| ISSN号 | 待补充 |
| 产权排序 | 1,1 |
| 通讯作者 | 李灿 |
| 中文摘要 | ultra-deep oxidative desulfurization of fuel oil catalyzed by dawson-type polyoxotungstate emulsion catalysts |
| 英文摘要 | the dawson-type polyoxotungstate emulsion catalysts q(18)p(2)w(18), q(18)p(2)w(17), and q(18)p(2)w(12) were successfully synthesized and characterized by ir and (31)p mas nmr. they were used for the oxidation of sulfur-containing compounds such as 4,6-dimethyldibenzothiophene (4,6-dmdbt), dibenzothiophene (dbt), benzothiophene (bt), and 2,5-dimethythiophene (2,5-dmt) with h(2)o(2) as an oxidant under mild conditions. the activity of the catalysts decreased in the order: q(18)p(2)w(12) > q(18)p(2)w(17) > q(18)p(2)w(18). the oxidative reactivity of the sulfur-containing compounds decreased according to dbt > 4,6-dmdbt > bt > 2,5-dmt. bt was completely oxidized into the corresponding sulfone upon catalysis by q(18)p(2)w(12) at 60 degrees c for 30 min. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | selective oxidation ; diesel ; hydrodesulfurization ; dibenzothiophene ; benzothiophene ; complexes |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000287951900005 |
| 公开日期 | 2012-07-09 |
| 源URL | [http://159.226.238.44/handle/321008/115762]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang Yongna,Wang Lu,Zhang Yuliang,et al. Ultra-deep Oxidative Desulfurization of Fuel Oil Catalyzed by Dawson-Type Polyoxotungstate Emulsion Catalysts[J]. chinese journal of catalysis,2011,32(2):235-239. |
| APA | Zhang Yongna,Wang Lu,Zhang Yuliang,Jiang Zongxuan,&Li Can.(2011).Ultra-deep Oxidative Desulfurization of Fuel Oil Catalyzed by Dawson-Type Polyoxotungstate Emulsion Catalysts.chinese journal of catalysis,32(2),235-239. |
| MLA | Zhang Yongna,et al."Ultra-deep Oxidative Desulfurization of Fuel Oil Catalyzed by Dawson-Type Polyoxotungstate Emulsion Catalysts".chinese journal of catalysis 32.2(2011):235-239. |
入库方式： OAI收割
来源：大连化学物理研究所
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