Determination of heat capacities and thermodynamic properties of two structurally unrelated but isotypic calcium and manganese(II) 2,6-naphthalene dicarboxylate-based MOFs
文献类型：期刊论文
| 作者 | Jiang, Chun-Hong1,2; Song, Li-Fang1,2; Jiao, Cheng-Li1,2; Zhang, Jian1; Sun, Li-Xian1; Xu, Fen3; Zhang, Huan-Zhi1; Xu, Qing-Yang1; Gabelica, Zelimir4 |
| 刊名 | journal of thermal analysis and calorimetry
 |
| 出版日期 | 2011-03-01 |
| 卷号 | 103期号:3页码:1095-1103 |
| 关键词 | Ca-MOF Mn-II-MOF Molar heat capacity TG Temperature-modulated DSC |
| ISSN号 | 1388-6150 |
| 产权排序 | 1,1 |
| 通讯作者 | 孙立贤 ; xufen |
| 中文摘要 | determination of heat capacities and thermodynamic properties of two structurally unrelated but isotypic calcium and manganese(ii) 2,6-naphthalene dicarboxylate-based mofs |
| 英文摘要 | two metal-organic frameworks, ca(2,6-ndc)(dmf) (1) and mn-3(2,6-ndc)(3)(dmf)(4) (2) (where 2,6-ndc = 2,6-naphthalene dicarboxylate and dmf = n,n'-dimethylformamide) have been solvothermally synthesized under optimized conditions and characterized by x-ray powder diffraction, elemental analysis, ft-ir spectroscopy, and tg analysis. the thermal decomposition characteristics were investigated under air atmosphere from 300 to 1,170 k (for 1) and from 300 to 971 k (for 2). the molar heat capacities were measured from 198 to 548 k (for 1) and from 198 to 448 k (for 2) by temperature modulated differential scanning calorimetry (tmdsc) for the first time. the fundamental thermodynamic parameters such as entropy and enthalpy variations with temperature were calculated based on the experimentally determined molar heat capacities. |
| WOS标题词 | science & technology ; physical sciences |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, analytical ; chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | metal-organic frameworks ; hydrogen sorption ; gas-adsorption ; photoluminescence ; storage ; separation ; catalysts ; co2 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000287712400040 |
| 公开日期 | 2012-07-09 |
| 源URL | [http://159.226.238.44/handle/321008/115776]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 3.Liaoning Normal Univ, Fac Chem & Chem Engn, Dalian 116029, Peoples R China 4.Univ Haute Alsace, ENSCMu, Lab LPI GSEC, F-68094 Mulhouse, France |
| 推荐引用方式 GB/T 7714 | Jiang, Chun-Hong,Song, Li-Fang,Jiao, Cheng-Li,et al. Determination of heat capacities and thermodynamic properties of two structurally unrelated but isotypic calcium and manganese(II) 2,6-naphthalene dicarboxylate-based MOFs[J]. journal of thermal analysis and calorimetry,2011,103(3):1095-1103. |
| APA | Jiang, Chun-Hong.,Song, Li-Fang.,Jiao, Cheng-Li.,Zhang, Jian.,Sun, Li-Xian.,...&Gabelica, Zelimir.(2011).Determination of heat capacities and thermodynamic properties of two structurally unrelated but isotypic calcium and manganese(II) 2,6-naphthalene dicarboxylate-based MOFs.journal of thermal analysis and calorimetry,103(3),1095-1103. |
| MLA | Jiang, Chun-Hong,et al."Determination of heat capacities and thermodynamic properties of two structurally unrelated but isotypic calcium and manganese(II) 2,6-naphthalene dicarboxylate-based MOFs".journal of thermal analysis and calorimetry 103.3(2011):1095-1103. |
入库方式： OAI收割
来源：大连化学物理研究所
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