Heat capacities and thermodynamic properties of MgNDC
文献类型：期刊论文
| 作者 | Song, Li-Fang1,2; Jiao, Cheng-Li1,2; Jiang, Chun-Hong1,2; Zhang, Jian1; Sun, Li-Xian1; Xu, Fen3; Jiao, Qing-Zhu3; Xing, Yong-Heng3; Huang, F. L.4; Du, Yong5 |
| 刊名 | journal of thermal analysis and calorimetry
 |
| 出版日期 | 2011 |
| 卷号 | 103期号:1页码:365-372 |
| ISSN号 | 1388-6150 |
| 关键词 | Magnesium TMDSC Metal-organic frameworks Molar heat capacity TG |
| 通讯作者 | 孙立贤 ; xufen |
| 产权排序 | 1,1 |
| 中文摘要 | heat capacities and thermodynamic properties of mgndc |
| 英文摘要 | one-three-dimensional metal-organic frameworks mg-1.5(c12h6o4)(1.5)(c3h7no)(2) (mgndc) has been synthesized solvothermally and characterized by single crystal xrd, powder xrd, ft-ir spectra. the low-temperature molar heat capacities of mgndc were measured by temperature modulated differential scanning calorimetry (tmdsc) over the temperature range from 205 to 470 k for the first time. no phase transition or thermal anomaly was observed in the experimental temperature range. the thermodynamic parameters of mgndc such as entropy and enthalpy relative to reference temperature of 298.15 k were derived based on the above molar heat capacities data. moreover, the thermal stability and decomposition of mgndc was further investigated through thermogravimetry (tg)-mass spectrometer (ms). three stages of mass loss were observed in the tg curve. tg-ms curve indicated that the oxidative degradation products of mgndc are mainly h2o, co2, no, and no2. |
| 学科主题 | 物理化学 |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, analytical ; chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | metal-organic frameworks ; coordination polymer ; modulated dsc |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000287714400053 |
| 公开日期 | 2012-07-09 |
| 源URL | [http://159.226.238.44/handle/321008/115778]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 3.Liaoning Normal Univ, Fac Chem & Chem Engn, Dalian 116029, Peoples R China 4.Beijing Inst Technol, State Key Lab Explos Sci & Technol, Beijing 100081, Peoples R China 5.Cent S Univ, State Key Lab Powder Met, Changsha 410083, Peoples R China 6.Changsha Univ Sci & Technol, Coll Chem & Biol Engn, Changsha 410076, Hunan, Peoples R China 7.Dalian Univ Technol, Lab Mat Modificat Laser Electron & Ion Beams, Dalian 116024, Peoples R China |
| 推荐引用方式 GB/T 7714 | Song, Li-Fang,Jiao, Cheng-Li,Jiang, Chun-Hong,et al. Heat capacities and thermodynamic properties of MgNDC[J]. journal of thermal analysis and calorimetry,2011,103(1):365-372. |
| APA | Song, Li-Fang.,Jiao, Cheng-Li.,Jiang, Chun-Hong.,Zhang, Jian.,Sun, Li-Xian.,...&Zhao, Jijun.(2011).Heat capacities and thermodynamic properties of MgNDC.journal of thermal analysis and calorimetry,103(1),365-372. |
| MLA | Song, Li-Fang,et al."Heat capacities and thermodynamic properties of MgNDC".journal of thermal analysis and calorimetry 103.1(2011):365-372. |
入库方式： OAI收割
来源：大连化学物理研究所
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