Microwave-promoted conversion of concentrated fructose into 5-hydroxymethylfurfural in ionic liquids in the absence of catalysts
文献类型：期刊论文
| 作者 | Li, Changzhi; Zhao, Zongbao K.; Cai, Haile; Wang, Aiqin; Zhang, Tao |
| 刊名 | biomass & bioenergy
 |
| 出版日期 | 2011-05-01 |
| 卷号 | 35期号:5页码:2013-2017 |
| 关键词 | Biofuel Carbohydrates 5-Hydroxymethylfurfural Ionic liquids Microwave irradiation Dehydration reaction |
| ISSN号 | 0961-9534 |
| 产权排序 | 1,1 |
| 通讯作者 | 赵宗保 ; 张涛 |
| 中文摘要 | microwave-promoted conversion of concentrated fructose into 5-hydroxymethylfurfural in ionic liquids in the absence of catalysts |
| 英文摘要 | under microwave irradiation, concentrated fructose (33-92 wt%) in ionic liquids afforded 5-hydroxymethylfurfural in ca. 97-57% yields without addition of catalysts, within 3 min. in-situ (13)c nmr and (1)h nmr spectra suggest that the transformation of fructose in ionic liquid is a highly selective reaction that proceeds predominantly via the cyclic fructofuransyl intermediate. this method is expected to be valuable in facilitating cost-effective conversion of carbohydrates into biofuels and platform chemicals. (c) 2011 elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; life sciences & biomedicine ; technology |
| 学科主题 | 物理化学 |
| 类目[WOS] | agricultural engineering ; biotechnology & applied microbiology ; energy & fuels |
| 研究领域[WOS] | agriculture ; biotechnology & applied microbiology ; energy & fuels |
| 关键词[WOS] | dehydration ; imidazolium ; chemistry ; mechanism ; biomass ; water |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000290238200049 |
| 公开日期 | 2012-07-09 |
| 源URL | [http://159.226.238.44/handle/321008/115816]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Changzhi,Zhao, Zongbao K.,Cai, Haile,et al. Microwave-promoted conversion of concentrated fructose into 5-hydroxymethylfurfural in ionic liquids in the absence of catalysts[J]. biomass & bioenergy,2011,35(5):2013-2017. |
| APA | Li, Changzhi,Zhao, Zongbao K.,Cai, Haile,Wang, Aiqin,&Zhang, Tao.(2011).Microwave-promoted conversion of concentrated fructose into 5-hydroxymethylfurfural in ionic liquids in the absence of catalysts.biomass & bioenergy,35(5),2013-2017. |
| MLA | Li, Changzhi,et al."Microwave-promoted conversion of concentrated fructose into 5-hydroxymethylfurfural in ionic liquids in the absence of catalysts".biomass & bioenergy 35.5(2011):2013-2017. |
入库方式： OAI收割
来源：大连化学物理研究所
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