Complete assignment of H-1 and C-13 NMR data for nine protopanaxatriol glycosides
文献类型：期刊论文
| 作者 | Teng, RW; Li, HZ; Chen, JT; Wang, DZ; He, YN; Yang, CR |
| 刊名 | MAGNETIC RESONANCE IN CHEMISTRY
 |
| 出版日期 | 2002-07-01 |
| 卷号 | 40期号:7页码:483-488 |
| 关键词 | NMR H-1 NMR C-13 NMR 2D NMR protopanaxatriol glycoside Panax notoginseng complete NMR assignments glycosylation shift effect |
| ISSN号 | 0749-1581 |
| 英文摘要 | Nine protopanaxatriol glycosides isolated from mild acid hydrolysis products of crude root saponins of Panax notoginseng were identified as 20(R)-ginsenoside-Rh1, 20(S)-ginsenoside-Rh1, ginsenoside-Rg1, -Re and -Rg2, notoginsenoside-R2 and -R1, a mixture of 25-hydroxy-20(S)-ginsenoside-Rh1 and its C-20 (R) epimer, ginsenoside-Rh4. The complete assignments of the H-1 and C-13 NMR chemical shifts for these glycosides were obtained by means of 2D NMR techniques, including H-1-H-1 COSY, ROESY, HMQC, HMBC and HMQC-TOCSY spectra. The glycosylation shift effect of protopanaxatriol and the differences in chemical shifts between 20(R)- and 20(S)-protopanaxatriol isomers are also discussed. Except for ginsenoside-Re and -Rg2, complete NMR assignments of the other seven glycosides are reported for the first time. Copyright (C) 2002 John Wiley Sons, Ltd. |
| 学科主题 | Chemistry, Multidisciplinary; Chemistry, Physical; Spectroscopy |
| 类目[WOS] | Chemistry, Multidisciplinary ; Chemistry, Physical ; Spectroscopy |
| 研究领域[WOS] | Chemistry ; Spectroscopy |
| 关键词[WOS] | NOTOGINSENG BURK CHEN,F.H ; PANAX-NOTOGINSENG ; DAMMARANE-SAPONINS ; TRITERPENE OLIGOGLYCOSIDES ; BIOACTIVE SAPONINS ; DRIED ROOT ; GINSENG |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000176373300013 |
| 公开日期 | 2012-07-24 |
| 源URL | [http://ir.kib.ac.cn/handle/151853/14235]  |
| 专题 | 昆明植物研究所_离退休 |
| 作者单位 | Chinese Acad Sci, Kunming Inst Bot, Kunming 650204, Yunnan, Peoples R China |
| 推荐引用方式 GB/T 7714 | Teng, RW,Li, HZ,Chen, JT,et al. Complete assignment of H-1 and C-13 NMR data for nine protopanaxatriol glycosides[J]. MAGNETIC RESONANCE IN CHEMISTRY,2002,40(7):483-488. |
| APA | Teng, RW,Li, HZ,Chen, JT,Wang, DZ,He, YN,&Yang, CR.(2002).Complete assignment of H-1 and C-13 NMR data for nine protopanaxatriol glycosides.MAGNETIC RESONANCE IN CHEMISTRY,40(7),483-488. |
| MLA | Teng, RW,et al."Complete assignment of H-1 and C-13 NMR data for nine protopanaxatriol glycosides".MAGNETIC RESONANCE IN CHEMISTRY 40.7(2002):483-488. |
入库方式： OAI收割
来源：昆明植物研究所
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