Study on superabsorbent composite—VII. Effects of organification of attapulgite on swelling behaviors of poly(acrylic acid-co-acrylamide)/sodium humate/organo-attapulgite composite
文献类型:期刊论文
作者 | Wang AQ(王爱勤)![]() ![]() |
刊名 | Polymers for Advanced Technologies
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出版日期 | 2006 |
卷号 | 17页码:379-385 |
关键词 | superabsorbent composites organification swelling networks |
ISSN号 | 1042-7147 |
通讯作者 | 王爱勤 aqwang@licp.cas.cn |
中文摘要 | A novel multifunctional superabsorbent composite from acrylic acid (AA), acrylamide (AM), sodium humate (SH) and organo-attapulgite (organo-APT), PAA-AM/SH/organo-APT, was synthesized by aqueous solution polymerization, using N,N′-methylenebisacrylamide (MBA) as a crosslinker and ammonium persulfate (APS) as an initiator. The organification of APT with hexadecyltrimethyl ammonium bromide (HDTMABr) was proved by FT-IR. The effects of organo-APT (HDTMA-APT) content in the superabsorbent composite and organification degree of it on water absorbency of the superabsorbent composite were studied. The effects of incorporated HDTMA-APT on swelling rate, water absorbency in various saline solutions and reswelling capability of the superabsorbent composite were also investigated. The results indicate that organification of APT had a remarkable influence on swelling behaviors of the superabsorbent composites. Comparing with the composite doped with APT, water absorbency for the composite incorporated with 10?wt% HDTMA-APT was enhanced from 996 to 1282?g?g?1 in distilled water and from 63 to 68?g?g?1 in 0.9?wt% NaCl solution, respectively. The superabsorbent composite acquired its highest water absorbency when the organification degree of APT was 8.02?wt%. Water absorbency of the composites in various saline solutions decreased with the increasing concentration, especially for the multivalent cations. In addition, swelling rate and reswelling capability of the superabsorbent composite were also improved by introducing HDTMA-APT into the composite compared with that of incorporating APT. |
学科主题 | 功能高分子 |
收录类别 | SCI |
资助信息 | The “863” major project of the Ministry of Science and Technology, P. R. China; contract/grant number: 2005AA2Z4030 |
语种 | 英语 |
公开日期 | 2012-09-02 |
源URL | [http://210.77.64.217/handle/362003/227] ![]() |
专题 | 兰州化学物理研究所_环境材料与生态化学研究发展中心 |
推荐引用方式 GB/T 7714 | Wang AQ,Zhang JP. Study on superabsorbent composite—VII. Effects of organification of attapulgite on swelling behaviors of poly(acrylic acid-co-acrylamide)/sodium humate/organo-attapulgite composite[J]. Polymers for Advanced Technologies,2006,17:379-385. |
APA | 王爱勤,&张俊平.(2006).Study on superabsorbent composite—VII. Effects of organification of attapulgite on swelling behaviors of poly(acrylic acid-co-acrylamide)/sodium humate/organo-attapulgite composite.Polymers for Advanced Technologies,17,379-385. |
MLA | 王爱勤,et al."Study on superabsorbent composite—VII. Effects of organification of attapulgite on swelling behaviors of poly(acrylic acid-co-acrylamide)/sodium humate/organo-attapulgite composite".Polymers for Advanced Technologies 17(2006):379-385. |
入库方式: OAI收割
来源:兰州化学物理研究所
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