Investigation on three new metal carboxydiphosphonates: Syntheses, structures, magnetic and luminescent properties
文献类型：期刊论文
| 作者 | Tang, Si-Fu; Pan, Xiao-Bo; Lv, Xiao-Xia; Zhao, Xue-Bo |
| 刊名 | JOURNAL OF SOLID STATE CHEMISTRY
 |
| 出版日期 | 2013 |
| 卷号 | 197期号:6页码:139-146 |
| 关键词 | Metal phosphonates Crystal structure Luminescence Magnetism |
| 英文摘要 | A new multifunctionalized phosphoric acid, (2-(diphosphonomethylamino)nicotinic acid, Py(COOH)(NHCH-(PO3H2)(2)), H5L1), has been employed as ligand for the construction of new metal phosphonates. By reacting it with different metal chlorides under hydrothermal condition, three new transition metal phosphonates, namely, [Co-2(HL1)(H2O)(5)H2O](3) (1), Zn(H3L1) (2) and [Cd(H3L1)(H2O)(2)][H2O] (3) were successfully obtained. The single-crystal structure measurements indicated that the coordination mode of ligand H5L1 is metal-dependant and results in different structures. For compound 1, it features 2D layered structure. Whereas compounds 2 and 3 have 1D chain structures. Under the excitation of 250 nm light, both compounds 2 and 3 show intraligand and ligand to metal charge transfer (LMCT) emission bands at about 415 and 420 nm, respectively. Magnetic study shows that compound 1 displays antiferromagnetic behavior. (C) 2012 Elsevier Inc. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 学科主题 | 储氢及新型纳孔材料 |
| 类目[WOS] | Chemistry, Inorganic & Nuclear ; Chemistry, Physical |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | LAYERED CADMIUM PHOSPHONATE ; RAY-POWDER STRUCTURES ; COORDINATION POLYMERS ; CRYSTAL-STRUCTURES ; CARBOXYLATE-PHOSPHONATES ; BUILDING-BLOCKS ; LIGANDS ; DIPHOSPHONATES ; FRAMEWORKS ; CD(II) |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000312281000019 |
| 公开日期 | 2012-09-11 |
| 源URL | [http://ir.qibebt.ac.cn:8080/handle/337004/1058]  |
| 专题 | 青岛生物能源与过程研究所_储氢及新型纳孔材料团队 |
| 作者单位 | Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tang, Si-Fu,Pan, Xiao-Bo,Lv, Xiao-Xia,et al. Investigation on three new metal carboxydiphosphonates: Syntheses, structures, magnetic and luminescent properties[J]. JOURNAL OF SOLID STATE CHEMISTRY,2013,197(6):139-146. |
| APA | Tang, Si-Fu,Pan, Xiao-Bo,Lv, Xiao-Xia,&Zhao, Xue-Bo.(2013).Investigation on three new metal carboxydiphosphonates: Syntheses, structures, magnetic and luminescent properties.JOURNAL OF SOLID STATE CHEMISTRY,197(6),139-146. |
| MLA | Tang, Si-Fu,et al."Investigation on three new metal carboxydiphosphonates: Syntheses, structures, magnetic and luminescent properties".JOURNAL OF SOLID STATE CHEMISTRY 197.6(2013):139-146. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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