Azide anion encapsulation in a tetraurea receptor
文献类型:期刊论文
作者 | Huang XJ(黄晓卷)![]() |
刊名 | Inorg. Chem. Commun.
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出版日期 | 2011 |
卷号 | 14期号:9页码:1508-1510 |
关键词 | Anion binding Tetraurea receptors Azide encapsulation N(urea)\H⋯N(azide) hydrogen bonding |
ISSN号 | 1387-7003 |
通讯作者 | 吴彪 |
中文摘要 | The azide complex [Na(15-crown-5)]2[L(N3)2] has been synthesized. X-ray single-crystal diffraction analysis revealed that two orthogonally oriented azide anions are encapsulated in one receptor, each by two opposite urea edges of the square tetreurea ligand through N(urea)−H⋯N(azide) hydrogen bonding. UV–vis titration confirmed the 1:2 (host/guest) binding mode in solution with slight bathochromic shifts compared to the ligand. |
学科主题 | 金属有机 |
收录类别 | SCI |
资助信息 | the National Natural Science Foundation of China (grant no. 20872149) |
语种 | 英语 |
WOS记录号 | WOS:000294532400047 |
公开日期 | 2012-09-20 |
源URL | [http://210.77.64.217/handle/362003/317] ![]() |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
推荐引用方式 GB/T 7714 | Huang XJ. Azide anion encapsulation in a tetraurea receptor[J]. Inorg. Chem. Commun.,2011,14(9):1508-1510. |
APA | 黄晓卷.(2011).Azide anion encapsulation in a tetraurea receptor.Inorg. Chem. Commun.,14(9),1508-1510. |
MLA | 黄晓卷."Azide anion encapsulation in a tetraurea receptor".Inorg. Chem. Commun. 14.9(2011):1508-1510. |
入库方式: OAI收割
来源:兰州化学物理研究所
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