One-step synthesis of chiral dimethyl 2-oxo-3-phenyl-glutarate in the asymmetric Triple-carbonylation of styrene
文献类型：期刊论文
| 作者 | Wang LL(王来来) ; Zhang QS(张勤生); Wang LL(王来来)
|
| 刊名 | Chin. J. Catal.
 |
| 出版日期 | 2011 |
| 卷号 | 32页码:1143-1148 |
| 关键词 | styrene asymmetric triple-carbonylation chiral dimethyl 2-oxo-3-phenyl-glutarate palladium 2 dipyridlphosphines 4-pentanedionate |
| ISSN号 | 1872-2067 |
| 通讯作者 | 王来来 |
| 中文摘要 | The in situ preparation of the novel chiral catalyst system, which are composed of (S)-2,2',6,6'-tetramethoxy- 4,4'-bis(diphenylphosphine)-3,3'-bipyridine ((S)-P-PHOS) and palladium 2,4-pentanedionate, have been described. These complexes were found to be effective in the asymmetric triple-carbonylation of styrene, reaching up to [ ]D 20 = +27o (c, 0.28, CH2Cl2) for dimethyl 2-oxo-3-phenyl-glutarate using benzoquinone as oxidant, p-toluenesulfonic acid as co-catalyst, and methanol as solvent. |
| 学科主题 | 有机功能材料 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (20343005, 20473107, 20673130, 20773147) |
| 语种 | 英语 |
| WOS记录号 | WOS:000293319300006 |
| 公开日期 | 2012-09-20 |
| 源URL | [http://210.77.64.217/handle/362003/343]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 通讯作者 | Wang LL(王来来); Wang LL(王来来) |
| 推荐引用方式 GB/T 7714 | Wang LL,Zhang QS,Wang LL. One-step synthesis of chiral dimethyl 2-oxo-3-phenyl-glutarate in the asymmetric Triple-carbonylation of styrene[J]. Chin. J. Catal.,2011,32:1143-1148. |
| APA | 王来来,张勤生,&王来来.(2011).One-step synthesis of chiral dimethyl 2-oxo-3-phenyl-glutarate in the asymmetric Triple-carbonylation of styrene.Chin. J. Catal.,32,1143-1148. |
| MLA | 王来来,et al."One-step synthesis of chiral dimethyl 2-oxo-3-phenyl-glutarate in the asymmetric Triple-carbonylation of styrene".Chin. J. Catal. 32(2011):1143-1148. |
入库方式： OAI收割
来源：兰州化学物理研究所
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