2-β-Benzothiazolyl-6-iminopyridylmetal dichlorides and the catalytic behavior towards ethylene oligomerization and polymerization
文献类型：期刊论文
| 作者 | Song SJ(宋盛菊) ; Gao R(高榕) ; Zhang M(张民) ; Li Y(李言) ; Wang FS(王佛松) ; Sun WH(孙文华) |
| 刊名 | Inorg. Chim. Acta
 |
| 出版日期 | 2011 |
| 卷号 | 376页码:373-380 |
| 关键词 | 2-b-Benzothiazolyl-6-iminopyridine Iron Cobalt Oligomerization Polymerization |
| ISSN号 | 0020-1693 |
| 通讯作者 | 孙文华 |
| 中文摘要 | A series of 2-(2-benzothiazolyl)-6-(1-(arylimino)ethyl)pyridines and their metal (Fe or Co) complexes were prepared. All organic compounds were fully characterized by NMR, FT-IR spectra and elemental analysis, and all metal complexes were identified by FT-IR spectroscopic and elemental analysis. The molecular structures of representative metal complexes were confirmed by single-crystal X-ray diffraction and displayed the distorted trigonal bipyramid geometry. Upon activation with modified methylaluminoxane (MMAO), the iron pro-catalysts showed good catalytic activities up to the range of 107 g mol 1(Fe) h 1 in ethylene reactivity with the high selectivity for the vinyl-type products of both oligomers and polyethylene waxes; whereas the cobalt pro-catalysts showed moderate activities towards ethylene oligomerization. The correlations between metal complexes and their catalytic activities and products were investigated in detail under various reaction parameters and discussed. |
| 学科主题 | 物理化学 |
| 收录类别 | SCI |
| 资助信息 | NSFC No. 20874105;MOST 863 program No. 2009AA033601 |
| 语种 | 英语 |
| 公开日期 | 2012-09-20 |
| 源URL | [http://210.77.64.217/handle/362003/380]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Song SJ,Gao R,Zhang M,et al. 2-β-Benzothiazolyl-6-iminopyridylmetal dichlorides and the catalytic behavior towards ethylene oligomerization and polymerization[J]. Inorg. Chim. Acta,2011,376:373-380. |
| APA | 宋盛菊,高榕,张民,李言,王佛松,&孙文华.(2011).2-β-Benzothiazolyl-6-iminopyridylmetal dichlorides and the catalytic behavior towards ethylene oligomerization and polymerization.Inorg. Chim. Acta,376,373-380. |
| MLA | 宋盛菊,et al."2-β-Benzothiazolyl-6-iminopyridylmetal dichlorides and the catalytic behavior towards ethylene oligomerization and polymerization".Inorg. Chim. Acta 376(2011):373-380. |
入库方式： OAI收割
来源：兰州化学物理研究所
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