Synthesis, characterization and catalytic behavior toward ethylene of cobalt(II) and iron(II) complexes bearing 2-(1-aryliminoethylidene)quinolines
文献类型：期刊论文
| 作者 | Song SJ(宋盛菊) ; Zhao WZ(赵炜珍) ; Wang L(王林) ; Carl Redshaw ; Wang FS(王佛松) ; Sun WH(孙文华) |
| 刊名 | J. Organomet. Chem.
 |
| 出版日期 | 2011 |
| 卷号 | 696页码:3029-3035 |
| 关键词 | Ethylene dimerization 2-(1-Aryliminoethylidene)quinoline Cobalt Iron |
| ISSN号 | 0022-328X |
| 通讯作者 | 孙文华 |
| 中文摘要 | A series of 2-(1-aryliminoethylidene)quinolines (L) were synthesized and used as bidentate N^N ligands in coordinating with metal (cobalt and iron) chlorides to form complexes of the type LMCl2, cobalt(II) (Co1eCo5) and iron(II) (Fe1eFe5). All organic compounds and metal complexes were fully characterized, and the molecular structures of the representative complexes Co3$DMF and Fe4$DMF were confirmed as distorted bipyramidal geometry at the metal by single-crystal X-ray diffraction. Upon activation with either methylaluminoxane (MAO) or modified methylaluminoxane (MMAO) under 10 atm ethylene, all complexes showed high activities in ethylene dimerization with activities of up to 1.82 106 g mol 1 (Co) h 1 and 5.89 105 g mol 1 (Fe) h 1, respectively. |
| 学科主题 | 物理化学 |
| 收录类别 | SCI |
| 资助信息 | the MOST 863 program No. 2009AA033601 |
| 语种 | 英语 |
| WOS记录号 | WOS:000292726800015 |
| 公开日期 | 2012-09-20 |
| 源URL | [http://210.77.64.217/handle/362003/388]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Song SJ,Zhao WZ,Wang L,et al. Synthesis, characterization and catalytic behavior toward ethylene of cobalt(II) and iron(II) complexes bearing 2-(1-aryliminoethylidene)quinolines[J]. J. Organomet. Chem.,2011,696:3029-3035. |
| APA | 宋盛菊,赵炜珍,王林,Carl Redshaw,王佛松,&孙文华.(2011).Synthesis, characterization and catalytic behavior toward ethylene of cobalt(II) and iron(II) complexes bearing 2-(1-aryliminoethylidene)quinolines.J. Organomet. Chem.,696,3029-3035. |
| MLA | 宋盛菊,et al."Synthesis, characterization and catalytic behavior toward ethylene of cobalt(II) and iron(II) complexes bearing 2-(1-aryliminoethylidene)quinolines".J. Organomet. Chem. 696(2011):3029-3035. |
入库方式： OAI收割
来源：兰州化学物理研究所
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