Synthesis, Characterization, and Ethylene (Co)Polymerization Behavior of Trichlorotitanium 2-(1-(Arylimino)propyl)quinolin-8-olates
文献类型：期刊论文
| 作者 | Huang W(黄伟) ; Zhang WJ(张文娟) ; Liu SF(刘绍峰) ; Liang TL(梁同玲) ; Sun WH(孙文华) |
| 刊名 | J. Polym. Sci., Part A: Polym. Chem.
 |
| 出版日期 | 2011 |
| 卷号 | 49期号:8页码:1887-1894 |
| 关键词 | addition polymerization 2-(1-(arylimino)propyl)quinolin-8-olates copolymerization ethylene homopolymerization metal-organic catalysts/organometallic catalysts polyethylene (PE) trichlorotitanium pro-catalyst |
| ISSN号 | 1099-0518 |
| 通讯作者 | 孙文华 |
| 中文摘要 | A series of trichlorotitanium complexes containing 2-(1-(arylimino)propyl)quinolin-8-olates was synthesized by stoichiometric reaction of titanium tetrachloride with the corresponding potassium 2-(1-(arylimino)propyl)quinolin-8-olates and was fully characterized by elemental analysis, nuclear magnetic resonance spectroscopy, and by single-crystal X-ray diffraction study of representative complexes. All titanium complexes, when activated with methylaluminoxane, exhibited high catalytic activity toward ethylene polymerization [up to 1.15 106 g mol 1(Ti) h 1] and ethylene/a-olefin copolymerization [up to 1.54 106 g mol 1 (Ti) h 1]. The incorporation of comonomer was confirmed to amount up to 2.82 mol % of 1-hexene or 1.94 mol % of 1-octene, respectively. VC 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 49: 1887– 1894, 2011 |
| 学科主题 | 物理化学 |
| 收录类别 | SCI |
| 资助信息 | Natural Science Foundation of China (NSFC) (nos. 20874105;20904059);the Ministry of Science and Technology (MOST) 863 Program (no. 2009AA034601) |
| 语种 | 英语 |
| WOS记录号 | WOS:000288614000018 |
| 公开日期 | 2012-09-20 |
| 源URL | [http://210.77.64.217/handle/362003/389]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Huang W,Zhang WJ,Liu SF,et al. Synthesis, Characterization, and Ethylene (Co)Polymerization Behavior of Trichlorotitanium 2-(1-(Arylimino)propyl)quinolin-8-olates[J]. J. Polym. Sci., Part A: Polym. Chem.,2011,49(8):1887-1894. |
| APA | 黄伟,张文娟,刘绍峰,梁同玲,&孙文华.(2011).Synthesis, Characterization, and Ethylene (Co)Polymerization Behavior of Trichlorotitanium 2-(1-(Arylimino)propyl)quinolin-8-olates.J. Polym. Sci., Part A: Polym. Chem.,49(8),1887-1894. |
| MLA | 黄伟,et al."Synthesis, Characterization, and Ethylene (Co)Polymerization Behavior of Trichlorotitanium 2-(1-(Arylimino)propyl)quinolin-8-olates".J. Polym. Sci., Part A: Polym. Chem. 49.8(2011):1887-1894. |
入库方式： OAI收割
来源：兰州化学物理研究所
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