Copper(II) Complexes with N-(9-anthracenyl)-N'-(3-pyridyl) urea (L) and a Derivative of L: Synthesis, Structure, and Fluorescent Properties
文献类型：期刊论文
| 作者 | Yang XJ(杨晓娟) ; Huang XJ(黄晓卷)
|
| 刊名 | Z. Anorg. Allg. Chem.
 |
| 出版日期 | 2010 |
| 卷号 | 636页码:1998-2003 |
| 关键词 | N-(9-anthracenyl)-N'-(3-pyridyl)urea N-[10-(10-methoxy-anthronyl)]-N'-(3-pyridyl)urea Copper Fluorescence Supramolecular chemistry |
| ISSN号 | 0044-2313 |
| 通讯作者 | 杨晓娟 ; 吴彪 |
| 中文摘要 | Three copper(II) complexes, [Cu2(OAc)4L2]·2CH3OH (1), [CuBr2L'2(CH3OH)]·CH3OH (2a), and [CuBr2L'2(DMSO)]·0.5CH3OH (2b) {L = N-(9-anthracenyl)-N'-(3-pyridyl)urea and L' = N-[10-(10-methoxy-anthronyl)]-N'-(3-pyridyl)urea} have been synthesized by the reaction of L with the corresponding copper(II) salts. Complex 1 shows a dinuclear structure with a conventional “paddlewheel” motif, inwhich four acetate units bridge the two CuII ions. In complexes 2a and 2b, the anthracenyl ligand L has been converted to an anthronyl derivative L', and the central metal ion exhibits a distorted square pyramidal arrangement, with two pyridyl nitrogen atoms and two bromide ions defining the basal plane and the apical position is occupied by a solvent molecule (CH3OH in 2a and DMSO in 2b). |
| 学科主题 | 金属有机功能材料 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (Grant No. 20872149) |
| 语种 | 英语 |
| 公开日期 | 2012-09-21 |
| 源URL | [http://210.77.64.217/handle/362003/458]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 兰州化学物理研究所_ERC国家工程研究中心 |
| 通讯作者 | Yang XJ(杨晓娟) |
| 推荐引用方式 GB/T 7714 | Yang XJ,Huang XJ. Copper(II) Complexes with N-(9-anthracenyl)-N'-(3-pyridyl) urea (L) and a Derivative of L: Synthesis, Structure, and Fluorescent Properties[J]. Z. Anorg. Allg. Chem.,2010,636:1998-2003. |
| APA | 杨晓娟,&黄晓卷.(2010).Copper(II) Complexes with N-(9-anthracenyl)-N'-(3-pyridyl) urea (L) and a Derivative of L: Synthesis, Structure, and Fluorescent Properties.Z. Anorg. Allg. Chem.,636,1998-2003. |
| MLA | 杨晓娟,et al."Copper(II) Complexes with N-(9-anthracenyl)-N'-(3-pyridyl) urea (L) and a Derivative of L: Synthesis, Structure, and Fluorescent Properties".Z. Anorg. Allg. Chem. 636(2010):1998-2003. |
入库方式： OAI收割
来源：兰州化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。