2-Ethyl-ketimino-1,10-phenanthroline iron(II) complexes as highly active catalysts for ethylene oligomerization
文献类型：期刊论文
| 作者 | Zhang M(张民) ; Zhang WJ(张文娟) ; 肖田鹏飞 ; Xiang JF(向俊峰) ; Hao X(郝项) ; Sun WH(孙文华) |
| 刊名 | J. Mol. Catal. A: Chem.
 |
| 出版日期 | 2010 |
| 卷号 | 320页码:92-96 |
| 关键词 | 2-Ethyl-ketimino-1 Iron(II) complexes Ethylene oligomerization 10-phenanthroline |
| ISSN号 | 1381-1169 |
| 通讯作者 | 孙文华 |
| 中文摘要 | A series of 2-(1-aryliminopropyl)-1,10-phenanthrolines (L1–L7) and their corresponding iron(II) chlorides (Fe1–Fe7) are synthesized and characterized by elemental and spectroscopic analyses. The molecular structures of 2-[1-(2,6-diisopropy1phenylimino)propyl]-1,10-phenanthroline (L3) and {2-[1-(2,6-diethylphenylimino)propyl]-1,10-phenanthroline}·FeCl2 (Fe2) are determined by the single crystal X-ray diffraction. All iron complexes, activated with methylaluminoxane (MAO), exhibit high activities in ethylene oligomerization with high selectivity for -olefins produced. Compared with other 2-iminophenanthrolines, the title complexes show better thermal stability, and their oligomerization products are potentially more useful due to lower contents of butenes and waxes observed. |
| 学科主题 | 物理化学 |
| 收录类别 | SCI |
| 资助信息 | NSFC no. 20674089 |
| 语种 | 英语 |
| WOS记录号 | WOS:000276011600014 |
| 公开日期 | 2012-09-21 |
| 源URL | [http://210.77.64.217/handle/362003/476]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Zhang M,Zhang WJ,肖田鹏飞,et al. 2-Ethyl-ketimino-1,10-phenanthroline iron(II) complexes as highly active catalysts for ethylene oligomerization[J]. J. Mol. Catal. A: Chem.,2010,320:92-96. |
| APA | 张民,张文娟,肖田鹏飞,向俊峰,郝项,&孙文华.(2010).2-Ethyl-ketimino-1,10-phenanthroline iron(II) complexes as highly active catalysts for ethylene oligomerization.J. Mol. Catal. A: Chem.,320,92-96. |
| MLA | 张民,et al."2-Ethyl-ketimino-1,10-phenanthroline iron(II) complexes as highly active catalysts for ethylene oligomerization".J. Mol. Catal. A: Chem. 320(2010):92-96. |
入库方式： OAI收割
来源：兰州化学物理研究所
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