Asymmetric hydrogenation of aromatic ketones using new chiral- bridged diphosphine/diamine–Ru(II) complexes
文献类型：期刊论文
| 作者 | Wang LL(王来来) ; Sun W(孙伟); Wang LL(王来来)
|
| 刊名 | Chin. Chem. Lett.
 |
| 出版日期 | 2010 |
| 卷号 | 21页码:1403-1406 |
| 关键词 | Asymmetric hydrogenation Chiral alcohols Diphosphine ligand Ruthenium complexes Diamine |
| ISSN号 | 1001- 8417 |
| 通讯作者 | 王来来 ; Fuk Yee Kwong |
| 中文摘要 | A series of chiral secondary alcohols were easily prepared by means of asymmetric hydrogenation of prochiral aromatic ketones using a new ((Rax)-BuP)/(R,R)-DPEN–Ru(II) complex catalyst system. The hydrogenation of 2-methylacetophenone in n-butanol (t-BuOK/Ru = 45.6/1, S/C = 500, 20 atm. of H2, 20 8C, 48 h) afforded (S)-1-(20-methylphenyl)ethanol in 92% ee and >99% conversion. |
| 学科主题 | 有机功能材料 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (Nos. 20343005;20473107;20673130;20773147);the Hong Kong PolyU Joint Supervision Scheme (A-PH78) |
| 语种 | 英语 |
| 公开日期 | 2012-09-21 |
| 源URL | [http://210.77.64.217/handle/362003/477]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 通讯作者 | Wang LL(王来来); Wang LL(王来来) |
| 推荐引用方式 GB/T 7714 | Wang LL,Sun W,Wang LL. Asymmetric hydrogenation of aromatic ketones using new chiral- bridged diphosphine/diamine–Ru(II) complexes[J]. Chin. Chem. Lett.,2010,21:1403-1406. |
| APA | 王来来,孙伟,&王来来.(2010).Asymmetric hydrogenation of aromatic ketones using new chiral- bridged diphosphine/diamine–Ru(II) complexes.Chin. Chem. Lett.,21,1403-1406. |
| MLA | 王来来,et al."Asymmetric hydrogenation of aromatic ketones using new chiral- bridged diphosphine/diamine–Ru(II) complexes".Chin. Chem. Lett. 21(2010):1403-1406. |
入库方式： OAI收割
来源：兰州化学物理研究所
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