Design and synthesis of a tridentate ligand inspired by the phenomenon of self-assembly catalysis and its application in the asymmetric alkynylation of N-(diphenylphosphinoyl) imines
文献类型：期刊论文
| 作者 | Yan WJ(阎文锦) ; Li P(李鹏) ; Feng JC(冯静超) ; Wang D(王东) ; Zhu SQ(朱绍群) ; Jiang XX(蒋先兴) ; Wang R(王锐) |
| 刊名 | Tetrahedron: Asymmetry
 |
| 出版日期 | 2010 |
| 卷号 | 21页码:2037-2042 |
| ISSN号 | 0957-4166 |
| 通讯作者 | 王锐 |
| 中文摘要 | On the basis of the phenomenon of self-assembly catalysis, a tridentate ligand was designed and synthesized in two steps. The application in alkynylation of N-(diphenylphosphinoyl) imines gave the expected products. Aromatic, heteroaromatic N-(diphenylphosphinoyl) imines were employed and gave optically active propargylic amines in good yields (up to 89%) and excellent enantioselectivities (up to 96%) by a simple experimental procedure. The direct use of sulfone amides in the alkynylation of N-(diphenylphosphinoyl) aliphatic imines made this method very attractive. |
| 学科主题 | 物理化学 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (Nos. 20932003 ;90813012);the National S & T Major Project of China (2009ZX09503-017) |
| 语种 | 英语 |
| WOS记录号 | WOS:000281977500015 |
| 公开日期 | 2012-09-21 |
| 源URL | [http://210.77.64.217/handle/362003/515]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Yan WJ,Li P,Feng JC,et al. Design and synthesis of a tridentate ligand inspired by the phenomenon of self-assembly catalysis and its application in the asymmetric alkynylation of N-(diphenylphosphinoyl) imines[J]. Tetrahedron: Asymmetry,2010,21:2037-2042. |
| APA | 阎文锦.,李鹏.,冯静超.,王东.,朱绍群.,...&王锐.(2010).Design and synthesis of a tridentate ligand inspired by the phenomenon of self-assembly catalysis and its application in the asymmetric alkynylation of N-(diphenylphosphinoyl) imines.Tetrahedron: Asymmetry,21,2037-2042. |
| MLA | 阎文锦,et al."Design and synthesis of a tridentate ligand inspired by the phenomenon of self-assembly catalysis and its application in the asymmetric alkynylation of N-(diphenylphosphinoyl) imines".Tetrahedron: Asymmetry 21(2010):2037-2042. |
入库方式： OAI收割
来源：兰州化学物理研究所
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