Reaction of (Carbonyl)triruthenium with Acetylferrocene Thiosemicarbazone: Synthesis, X-ray Diffraction, and Insight into the Solution Structures
文献类型：期刊论文
| 作者 | Xia CG(夏春谷) ; Xia CG(夏春谷); Hu XX(胡霄雪); Hu B(胡斌)
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| 刊名 | European Journal of Inorganic Chemistry
 |
| 出版日期 | 2008 |
| 页码 | 5617-5621 |
| 关键词 | Ruthenium Carbonyl ligands Multinuclear compounds Structure elucidation |
| ISSN号 | 1434-1948 |
| 通讯作者 | 夏春谷 |
| 中文摘要 | Reaction of acetylferrocene thiosemicarbazone [L] with Ru3(CO)12 was investigated. Two new complexes, Ru3(CO)9-[L-H] (1) and Ru2(CO)4[L]2 (2) were isolated. They were characterized by IR, 1H NMR, and 13C NMR spectroscopic analysis. The crystal structures of 1 and 2 were also determined. In trinuclear cluster 1, the acetylferrocene thiosemicarbazone ligand was deprotonated and acted as an N,S-chelating ligand as well as a sulfur bridge. Dinuclear compound 2 is the first bis(cycloruthenated acetylferrocene thiosemicarbazone) carbonyl derivative. This complex contains two ruthenium atoms in a dinuclear structure with a Cferrocene, N, S2, and (CO)2 coordination sphere for each ruthenium atom, as both L ligands act as a Cferrocene, N, S2 chelate, and sulfur bridge. The behavior of 1 and 2 under electrospray ionization mass spectrometry (ESI-MS) was studied and the key intermediate Ru(CO)2[L-H] (3) in the formation of 2 was directly detected in the reaction solution. |
| 学科主题 | 清洁催化与生物转化 |
| 收录类别 | SCI |
| 资助信息 | the National Science Fund for Distinguished Young Scholars of China (No. 20625308) |
| 语种 | 英语 |
| WOS记录号 | WOS:000262312100009 |
| 公开日期 | 2012-09-21 |
| 源URL | [http://210.77.64.217/handle/362003/563]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 通讯作者 | Xia CG(夏春谷); Xia CG(夏春谷) |
| 推荐引用方式 GB/T 7714 | Xia CG,Xia CG,Hu XX,et al. Reaction of (Carbonyl)triruthenium with Acetylferrocene Thiosemicarbazone: Synthesis, X-ray Diffraction, and Insight into the Solution Structures[J]. European Journal of Inorganic Chemistry,2008:5617-5621. |
| APA | 夏春谷,夏春谷,胡霄雪,&胡斌.(2008).Reaction of (Carbonyl)triruthenium with Acetylferrocene Thiosemicarbazone: Synthesis, X-ray Diffraction, and Insight into the Solution Structures.European Journal of Inorganic Chemistry,5617-5621. |
| MLA | 夏春谷,et al."Reaction of (Carbonyl)triruthenium with Acetylferrocene Thiosemicarbazone: Synthesis, X-ray Diffraction, and Insight into the Solution Structures".European Journal of Inorganic Chemistry (2008):5617-5621. |
入库方式： OAI收割
来源：兰州化学物理研究所
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