Chromium(III) complexes bearing 2-benzoxazolyl-6-arylimino-pyridines: Synthesis and their ethylene reactivity
文献类型：期刊论文
| 作者 | Gao R(高榕) ; Liang TL(梁同玲) ; Wang FS(王佛松) ; Sun WH(孙文华) |
| 刊名 | Journal of Organometallic Chemistry
 |
| 出版日期 | 2009 |
| 卷号 | 694页码:3701-3707 |
| 关键词 | Chromium(III) complex 2-Benzoxazolyl-6-aryliminopyridine Ethylene oligomerization Ethylene polymerization |
| ISSN号 | 0022-328X |
| 通讯作者 | 孙文华 |
| 中文摘要 | A series of chromium(III) complexes bearing 2-benzoxazolyl-6-aryliminopyridines was synthesized and characterized by IR spectroscopic and CHN analysis. The X-ray crystallographic analysis of complex Cr3 revealed a distorted octahedral geometry. When activated by Et2AlCl, MAO or MMAO, these chromium complexes exhibited activities towards ethylene reactivity. High activities of ethylene oligomerization (up to 9.19 106 g mol 1 (Cr) h 1) were observed in the catalytic system using MMAO as a cocatalyst, meanwhile good activities of ethylene polymerization were achieved (up to 5.20 105 g mol 1 (Cr) h 1) by using MAO as a cocatalyst. Various reaction parameters were investigated in detail, and the steric and electronic effects of ligands were discussed. |
| 学科主题 | 物理化学 |
| 收录类别 | SCI |
| 资助信息 | NSFC No. 20674089 |
| 语种 | 英语 |
| WOS记录号 | WOS:000270369400004 |
| 公开日期 | 2012-09-21 |
| 源URL | [http://210.77.64.217/handle/362003/585]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Gao R,Liang TL,Wang FS,et al. Chromium(III) complexes bearing 2-benzoxazolyl-6-arylimino-pyridines: Synthesis and their ethylene reactivity[J]. Journal of Organometallic Chemistry,2009,694:3701-3707. |
| APA | 高榕,梁同玲,王佛松,&孙文华.(2009).Chromium(III) complexes bearing 2-benzoxazolyl-6-arylimino-pyridines: Synthesis and their ethylene reactivity.Journal of Organometallic Chemistry,694,3701-3707. |
| MLA | 高榕,et al."Chromium(III) complexes bearing 2-benzoxazolyl-6-arylimino-pyridines: Synthesis and their ethylene reactivity".Journal of Organometallic Chemistry 694(2009):3701-3707. |
入库方式： OAI收割
来源：兰州化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。