Asymmetric Direct Aldol Reactions Catalyzed by a Simple Chiral Primary Diamine–Brønsted Acid Catalyst in/on Water
文献类型：期刊论文
| 作者 | Li L(李莉) ; Xu LW(徐利文) ; Ju YD(鞠亚东) ; Lai GQ(来国桥) |
| 刊名 | Synthetic Communications
 |
| 出版日期 | 2009 |
| 卷号 | 39页码:764-774 |
| 关键词 | Aldol asymmetric catalysis organocatalysis primary amine water |
| ISSN号 | 0039-7911 |
| 通讯作者 | 徐利文 |
| 中文摘要 | The direct asymmetric aldol reaction catalyzed by the simple and commercially available chiral primary diamines, (1S,2S)-1,2-diphenylethane-1,2-diamine and (1R,2R)-1,2-diphenylethane-1,2-diamine, is presented. The catalyst system is a primary amine with Brønsted acid–catalyzed direct aldol reaction of p-nitrobenzaldehyde and cyclohexanone with high chemo- and stereoselectivity on water, which furnishes the corresponding b-hydroxyketone with up to 94% ee. |
| 学科主题 | 物理化学 |
| 收录类别 | SCI |
| 资助信息 | the Natural Science Foundation of China (NSFC No. 20572114);Hangzhou Normal University |
| 语种 | 英语 |
| 公开日期 | 2012-09-21 |
| 源URL | [http://210.77.64.217/handle/362003/597]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Li L,Xu LW,Ju YD,et al. Asymmetric Direct Aldol Reactions Catalyzed by a Simple Chiral Primary Diamine–Brønsted Acid Catalyst in/on Water[J]. Synthetic Communications,2009,39:764-774. |
| APA | 李莉,徐利文,鞠亚东,&来国桥.(2009).Asymmetric Direct Aldol Reactions Catalyzed by a Simple Chiral Primary Diamine–Brønsted Acid Catalyst in/on Water.Synthetic Communications,39,764-774. |
| MLA | 李莉,et al."Asymmetric Direct Aldol Reactions Catalyzed by a Simple Chiral Primary Diamine–Brønsted Acid Catalyst in/on Water".Synthetic Communications 39(2009):764-774. |
入库方式： OAI收割
来源：兰州化学物理研究所
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