Styrene epoxidation over Ag-c-ZrP catalyst prepared by ion-exchange
文献类型：期刊论文
| 作者 | Liu JH(刘俊华) ; Wang F(王芳) ; Gu ZG(顾正贵) ; Xu XL(徐贤伦) |
| 刊名 | Catalysis Communications
 |
| 出版日期 | 2009 |
| 卷号 | 10页码:868-871 |
| 关键词 | Epoxidation Styrene Silver Zirconium phosphates |
| ISSN号 | 1566-7367 |
| 通讯作者 | 刘俊华 |
| 中文摘要 | A hybrid complex Zr(PO4)(AgHPO4) was prepared by ion-exchange and was determined using elemental analysis, X-ray diffraction (XRD), Fourier transformed-infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS) and other instruments. Its catalytic activity was examined on the oxidation of styrene using t-butylhydroperoxide (TBHP) as oxidant under argon atmosphere, this system showed good epoxidation selectivity, the other factors, such as solvent, reaction time, concentrations of oxidant and catalyst, also have been investigated and reaction conditions are optimized. It is a novel highly active/selective and reusable heterogeneous catalyst for styrene epoxidation, while this catalytic system showed no epoxidation selectivity but good enol selectivity for cycloolefins with allylic H. |
| 学科主题 | 物理化学 |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2012-09-21 |
| 源URL | [http://210.77.64.217/handle/362003/640]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 兰州化学物理研究所_绿色化学研究发展中心 |
| 推荐引用方式 GB/T 7714 | Liu JH,Wang F,Gu ZG,et al. Styrene epoxidation over Ag-c-ZrP catalyst prepared by ion-exchange[J]. Catalysis Communications,2009,10:868-871. |
| APA | 刘俊华,王芳,顾正贵,&徐贤伦.(2009).Styrene epoxidation over Ag-c-ZrP catalyst prepared by ion-exchange.Catalysis Communications,10,868-871. |
| MLA | 刘俊华,et al."Styrene epoxidation over Ag-c-ZrP catalyst prepared by ion-exchange".Catalysis Communications 10(2009):868-871. |
入库方式： OAI收割
来源：兰州化学物理研究所
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