Synthesis and characterization of chitosan-based schiff base compounds with aromatic substituent groups
文献类型：期刊论文
| 作者 | Jiao TF(焦体峰) ; Zhou J(周娟) ; Zhou JX(周靖欣) ; Gao LH(高丽华) ; Xing YY(邢媛媛) ; Li XH(李旭辉) |
| 刊名 | Iranian Polymer Journal
 |
| 出版日期 | 2011 |
| 卷号 | 20期号:2页码:123-136 |
| 关键词 | chitosan Schiff base FTIR spectra thermal analysis X-ray diffraction |
| ISSN号 | 1026-1265 |
| 通讯作者 | 焦体峰 |
| 中文摘要 | Chitosan is the product of N-deacetylation of chitin. For its innocuous, renewable, biocompatible property chitosan is applied in many fields e.g., pharmaceutical, food, catalysis, material. In this work, three chitosan-based Schiff-based (CSB) compounds with aromatic substituent groups were synthesized from the reaction of chitosan with different aromatic aldehydes i.e., salicylaldehyde, 4-hexadecyloxy-2- hydroxybenzaldehyde and 2-hydroxy-1-naphthaldehyde. The chitosan-based Schiff base copper (II) complexes (CSBCu) were subsequently obtained through the reaction of relative Schiff bases with copper acetate. These products were characterized by elementary analysis (EA), Fourier transform infrared (FTIR) spectroscopy, thermal analysis (TG-DSC, TG-DTA), and X-ray diffraction (XRD) spectra, respectively. Generally, elemental analysis data may confirm the formation of chitosan-Schiff base as well as the coordination reaction of CSB with copper ions. FTIR analysis indicated that Schiff base and coordination reaction take place in Schiff base skeleton. Moreover, with the difference in substituent groups and spacer, FTIR spectra showed the clear variety. Thermal analysis showed that the thermal stability of CSB increased slightly, while that of the copper complexes was reduced significantly in comparison with chitosan. The XRD results demonstrated the appearance of a new crystallization peak of CSB in the vicinity of five degree and the lower crystallinity of CSBCu. The differences in crystallinity and thermal stability are mainly attributed to the formation of Schiff base group and complexation with copper ions, as well as spatially partial hindrance and hydrophobic forces in the aromatic substituent groups. The present results show that the specific properties of chitosan-based Schiff base derivatives can be altered by modifying the molecular structures of objective compounds with proper substituent groups. |
| 学科主题 | 材料科学与物理化学 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (NO.20903078);the Natural Science Foundation of Hebei Province (NO.B2009000347);Hundred Excellent Innovation Talents from Universities and Colleges of Hebei Province (NO.CPRC020);the Open Foundation of State Key Laboratory of Solid Lubrication (Lanzhou Institute of Chemical Physics,CAS) (NO.1002);the Scientific Research Plan of Education Department of Hebei Province (NO.Z2009146);the Scientific and Technological Research and Development Program of Qinhuangdao City (NO.201001A100;NO.201001A101);the Doctoral Foundation of Yanshan University (NO.B360) |
| 语种 | 英语 |
| WOS记录号 | WOS:000288833200003 |
| 公开日期 | 2012-09-24 |
| 源URL | [http://210.77.64.217/handle/362003/712]  |
| 专题 | 兰州化学物理研究所_固体润滑国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Jiao TF,Zhou J,Zhou JX,et al. Synthesis and characterization of chitosan-based schiff base compounds with aromatic substituent groups[J]. Iranian Polymer Journal,2011,20(2):123-136. |
| APA | 焦体峰,周娟,周靖欣,高丽华,邢媛媛,&李旭辉.(2011).Synthesis and characterization of chitosan-based schiff base compounds with aromatic substituent groups.Iranian Polymer Journal,20(2),123-136. |
| MLA | 焦体峰,et al."Synthesis and characterization of chitosan-based schiff base compounds with aromatic substituent groups".Iranian Polymer Journal 20.2(2011):123-136. |
入库方式： OAI收割
来源：兰州化学物理研究所
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