Enhanced electrogenerated chemiluminescence of Ru(bpy)(3)(2+)/tripropylamine system on indium tin oxide nanoparticle modified transparent electrode
文献类型：期刊论文
| 作者 | Huang, Rongfu ; Wei, Ming-Yuan ; Guo, Liang-Hong |
| 刊名 | JOURNAL OF ELECTROANALYTICAL CHEMISTRY
 |
| 出版日期 | 2011-06-15 |
| 卷号 | 656期号:*页码:136—139 |
| 中文摘要 | Electrochemiluminescence (ECL) systems using Ru(bpy)(3)(2+) (bpy = 2,2'-bipyridyl) and tripropylamine (TPA) on metal and carbon electrodes are widely used in immunoassay and DNA hybridization detections. The large overpotential of TPA oxidation on indium tin oxide (ITO) electrodes has limited their ECL application. In this work, significant enhancement of ECL signal from the Ru(bpy)(3)(2+)/TPA system was achieved on ITO nanoparticle-modified electrode. Due to the electrocatalytic activity of ITO nanoparticle electrodes, TPA oxidation potential was found to shift negatively by 600 mV, leading to 24-fold increases in ECL peak intensity over the conventional ITO electrode, and 2-fold increases in the integrated signal over the conventional gold electrode. As a result, the detection limit for Ru(bpy)(3)(2+) in solution was 20-fold lower than the value on the conventional ITO electrode. Because the transmittance of ITO at 610 nm (the wavelength of Ru(bpy)(3)(2+) emission maximum) was reduced only slightly after nanoparticle modification, it may offer a better alternative than metal and carbon electrodes in ECL measurements. (C) 2010 Elsevier B.V. All rights reserved. |
| WOS记录号 | WOS:000291768300022 |
| 公开日期 | 2012-10-16 |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/7040]  |
| 专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Huang, Rongfu,Wei, Ming-Yuan,Guo, Liang-Hong. Enhanced electrogenerated chemiluminescence of Ru(bpy)(3)(2+)/tripropylamine system on indium tin oxide nanoparticle modified transparent electrode[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY,2011,656(*):136—139. |
| APA | Huang, Rongfu,Wei, Ming-Yuan,&Guo, Liang-Hong.(2011).Enhanced electrogenerated chemiluminescence of Ru(bpy)(3)(2+)/tripropylamine system on indium tin oxide nanoparticle modified transparent electrode.JOURNAL OF ELECTROANALYTICAL CHEMISTRY,656(*),136—139. |
| MLA | Huang, Rongfu,et al."Enhanced electrogenerated chemiluminescence of Ru(bpy)(3)(2+)/tripropylamine system on indium tin oxide nanoparticle modified transparent electrode".JOURNAL OF ELECTROANALYTICAL CHEMISTRY 656.*(2011):136—139. |
入库方式： OAI收割
来源：生态环境研究中心
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