Ammonium removal from aqueous solution by zeolites synthesized from low-calcium and high-calcium fly ashes
文献类型：期刊论文
| 作者 | Zhang, Mulan ; Zhang, Huayong ; Xu, Dan ; Han, Lu ; Niu, Dongxiao ; Zhang, Luyi ; Wu, Wensi ; Tian, Binghui |
| 刊名 | DESALINATION
 |
| 出版日期 | 2011-08-15 |
| 卷号 | 277期号:*页码:46—53 |
| 中文摘要 | In this study, zeolites are synthesized from low-calcium (LC-Z) and high-calcium (HC-Z) fly ashes, respectively. The changes of mineralogy, morphology, cation exchange capacity (CEC) and specific surface area (SSA) are investigated during the synthesis process. The equilibrium uptake of ammonium on the two synthesized zeolites is compared. The main crystals of LC-Z and HC-Z are identified as faujasite and gismondine, respectively. The CEC and SSA increase significantly following the conversion process. The kinetic studies showed that the adsorption process of ammonium on both LC-Z and HC-Z follows Ho's pseudo-second-order model. Langmuir model agrees better with the equilibrium data for LC-Z, while Freundlich model gives the better fit for HC-Z. The obtained maximum ammonium uptake capacities are 23.8 mg/g for LC-Z and 3.17 mg/g for HC-Z in the synthetic solution. LC-Z also exhibits much better performance in ammonium uptake in effluent from a sewage treatment plant than HC-Z. These results indicate that LC-Z is a promising material for ammonium removal whereas HC-Z is not. The Ca(2+) leaching and the lower zeolite content in HC-Z account for its lower uptake capacity. Thus, the low-calcium fly ash should be chosen preferentially as the raw material of the zeolite synthesis for ammonium removal. (C) 2011 Elsevier B.V. All rights reserved. |
| WOS记录号 | WOS:000293720600006 |
| 公开日期 | 2012-10-16 |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/7014]  |
| 专题 | 生态环境研究中心_环境水质学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Zhang, Mulan,Zhang, Huayong,Xu, Dan,et al. Ammonium removal from aqueous solution by zeolites synthesized from low-calcium and high-calcium fly ashes[J]. DESALINATION,2011,277(*):46—53. |
| APA | Zhang, Mulan.,Zhang, Huayong.,Xu, Dan.,Han, Lu.,Niu, Dongxiao.,...&Tian, Binghui.(2011).Ammonium removal from aqueous solution by zeolites synthesized from low-calcium and high-calcium fly ashes.DESALINATION,277(*),46—53. |
| MLA | Zhang, Mulan,et al."Ammonium removal from aqueous solution by zeolites synthesized from low-calcium and high-calcium fly ashes".DESALINATION 277.*(2011):46—53. |
入库方式： OAI收割
来源：生态环境研究中心
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