Catalytic oxidation of benzene over nanostructured porous Co3O4-CeO2 composite catalysts
文献类型:期刊论文
作者 | Ma, Chunyan ; Mu, Zhen ; He, Chi ; Li, Peng ; Li, Jinjun ; Hao, Zhengping |
刊名 | JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA
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出版日期 | 2011 |
卷号 | 23期号:12页码:2078—2086 |
关键词 | benzene elimination nanocasting mesoporous Co3O4-CeO2 2D/3D structural Co/Ce ratios |
中文摘要 | Mesostructured Co3Co4-CeO2 composite was found to be an effective catalytic material for the complete oxidation of benzene. The Co3Co4-CeO2 catalysts with different Co/Ce ratios (mol/mol) were prepared via the nanocasting method and the mesostructure was replicated from two-dimensional (2D) hexagonal SBA-15 and three-dimensional (3D) cubic KIT-6 silicas, respectively. All the obtained Co3O4-CeO2 catalysts exhibited the similar symmetry with the parent silicas and well ordered mesostructures. The Co3O4-CeO2 catalysts with 2D mesostructure showed lower catalytic activities than the corresponding 3D meaterials. The Co3O4-Ceo(2) catalyst nanocasted from KIT-6 and with the Co/Ce ration of 16/1 possessed the best catalytic benzene oxidation activity due to larger quantities of surface hydroxyl groups and surface oxygenated species. The mesostructured Co3O4-CeO2 material thus shows great potential as a promising eco-environmental catalyst for benzene effective elimination. |
WOS记录号 | WOS:000298531000021 |
公开日期 | 2012-10-18 |
源URL | [http://ir.rcees.ac.cn/handle/311016/7141] ![]() |
专题 | 生态环境研究中心_环境纳米材料实验室 |
推荐引用方式 GB/T 7714 | Ma, Chunyan,Mu, Zhen,He, Chi,et al. Catalytic oxidation of benzene over nanostructured porous Co3O4-CeO2 composite catalysts[J]. JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA,2011,23(12):2078—2086. |
APA | Ma, Chunyan,Mu, Zhen,He, Chi,Li, Peng,Li, Jinjun,&Hao, Zhengping.(2011).Catalytic oxidation of benzene over nanostructured porous Co3O4-CeO2 composite catalysts.JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA,23(12),2078—2086. |
MLA | Ma, Chunyan,et al."Catalytic oxidation of benzene over nanostructured porous Co3O4-CeO2 composite catalysts".JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA 23.12(2011):2078—2086. |
入库方式: OAI收割
来源:生态环境研究中心
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