Simple indole-based colorimetric sensors with electron-withdrawing chromophores: tuning selectivity in anion sensing
文献类型：期刊论文
| 作者 | Guo Y(郭勇) ; Shao SJ(邵士俊); Shao SJ(邵士俊); Xu J(徐健); Guo Y(郭勇)
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| 刊名 | Journal of Fluorine Chemistry
 |
| 出版日期 | 2011 |
| 卷号 | 132页码:973-977 |
| 关键词 | Anion binding Indole Chromogenic sensor Deprotonation Spectroscopy |
| ISSN号 | 0022-1139 |
| 通讯作者 | 郭勇 ; 邵士俊 |
| 中文摘要 | Three simple colorimetric anion sensors (1, 2, and 3) containing anthrone, 1,3-indanedione, and malononitrile as signaling chromophores and an indole binding site have been designed and synthesized. The introduction of electron-withdrawing groups can not only provide chromogenic signal output, but also tune the sensitivity and selectivity of indole-based anion sensors by electron push–pull features. Their anion binding and sensing properties were investigated in detail by dramatic color changes, UV–vis absorption, and 1H NMR. As results revealed, sensor 1 showed high selectivity for F- over AcO- and H2PO4- with a distinct change in color due to the deprotonation of indole NH group. The excellent selectivity of 1 for F- can be attributed to the fitness in the acidity of its NH-group, which is tuned to be able to distinguish the subtle difference in the affinity of F-, AcO-, and H2PO4- to NH proton. |
| 学科主题 | 分析化学与药物化学 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (Grant No. 20972170 to S-J. Shao);the Natural Science Foundation of Gansu province (No. 096RJ2A033 to Y. Guo) |
| 语种 | 英语 |
| WOS记录号 | WOS:000295911100018 |
| 公开日期 | 2012-10-18 |
| 源URL | [http://210.77.64.217/handle/362003/1607]  |
| 专题 | 兰州化学物理研究所_中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 |
| 通讯作者 | Guo Y(郭勇); Shao SJ(邵士俊); Shao SJ(邵士俊); Guo Y(郭勇) |
| 推荐引用方式 GB/T 7714 | Guo Y,Shao SJ,Shao SJ,et al. Simple indole-based colorimetric sensors with electron-withdrawing chromophores: tuning selectivity in anion sensing[J]. Journal of Fluorine Chemistry,2011,132:973-977. |
| APA | 郭勇,邵士俊,邵士俊,徐健,&郭勇.(2011).Simple indole-based colorimetric sensors with electron-withdrawing chromophores: tuning selectivity in anion sensing.Journal of Fluorine Chemistry,132,973-977. |
| MLA | 郭勇,et al."Simple indole-based colorimetric sensors with electron-withdrawing chromophores: tuning selectivity in anion sensing".Journal of Fluorine Chemistry 132(2011):973-977. |
入库方式： OAI收割
来源：兰州化学物理研究所
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