Selective determination of uric acid in the presence of ascorbic acid at poly(p-aminobenzene sulfonic acid)-modified glassy carbon electrode
文献类型:期刊论文
作者 | Liu X(刘霞)![]() ![]() ![]() |
刊名 | Journal of Applied Electrochemistry
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出版日期 | 2009 |
卷号 | 39页码:2323-2328 |
关键词 | Glassy carbon electrode Electro-polymerization Uric acid Ascorbic acid Selective determination |
ISSN号 | 0021-891X |
通讯作者 | 蒋生祥 |
中文摘要 | The electrocatalytic behavior of uric acid has been investigated with a glassy carbon electrode modified with p-aminobenzene sulfonic acid through electrochemical polymerization. This resulting electrode shows an excellent electrocatalytic response to uric acid and ascorbic acid, with a peak-to-peak separation of 0.267 V in a 0.1 mol L-1 phosphate buffer solution (PBS) at pH 7.0. These results indicate that the proposed electrode can eliminate the serious interference of ascorbic acid, which coexists with uric acid in body fluids. Differential pulse voltammetry (DPV) was used for detecting uric acid with selectivity and sensitivity. The anodic peak current of uric acid was proportional to its concentration in the range of 1.2 9 10-7–8.0 9 10-4 mol L-1, with a detection limit of 4.0 9 10-8 mol L-1. The proposed method has been applied with satisfactory results to the determination of uric acid in human urine without any pretreatment. |
学科主题 | 分析化学与药物化学 |
收录类别 | SCI |
资助信息 | the National Natural Science Foundation of China (20527005, 20775084);the Natural Science Foundation of Gansu Province, China (3YS051-A25-022) |
语种 | 英语 |
WOS记录号 | WOS:000271734100003 |
公开日期 | 2012-09-29 |
源URL | [http://210.77.64.217/handle/362003/1183] ![]() |
专题 | 兰州化学物理研究所_中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 |
通讯作者 | Jiang SX(蒋生祥); Jiang SX(蒋生祥) |
推荐引用方式 GB/T 7714 | Liu X,Jiang SX,Jiang SX. Selective determination of uric acid in the presence of ascorbic acid at poly(p-aminobenzene sulfonic acid)-modified glassy carbon electrode[J]. Journal of Applied Electrochemistry,2009,39:2323-2328. |
APA | 刘霞,蒋生祥,&蒋生祥.(2009).Selective determination of uric acid in the presence of ascorbic acid at poly(p-aminobenzene sulfonic acid)-modified glassy carbon electrode.Journal of Applied Electrochemistry,39,2323-2328. |
MLA | 刘霞,et al."Selective determination of uric acid in the presence of ascorbic acid at poly(p-aminobenzene sulfonic acid)-modified glassy carbon electrode".Journal of Applied Electrochemistry 39(2009):2323-2328. |
入库方式: OAI收割
来源:兰州化学物理研究所
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