A highly selective amperometric sensor for ascorbic acid based on mesopore-rich active carbon-modified pyrolytic graphite electrode
文献类型：期刊论文
| 作者 | Shao SJ(邵士俊) ; Shao SJ(邵士俊); Guo Y(郭勇)
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| 刊名 | Electrochimica Acta
 |
| 出版日期 | 2010 |
| 卷号 | 55页码:2799-2804 |
| 关键词 | Mesopore-rich active carbon Pyrolytic graphite electrode Ascorbic acid Amperometric sensor |
| ISSN号 | 0013-4686 |
| 通讯作者 | 薛全民 ; 邵士俊 |
| 中文摘要 | A kind of new mesopore-rich active carbon (MRAC) was firstly prepared by carbonizing bamboo microparticles,which was utilized for constructing MRAC-modified pyrolytic graphite electrode (MRAC/PGE).The electrochemical behavior of ascorbic acid (AA) was in detail investigated at the MRAC/PGE. The proposed MRAC/PGE showed an excellent electrocatalytic response towards AA oxidation in neutral buffer solution. The oxidation potential of AA significantly decreased at MRAC/PGE. The oxidation current of AA obtained at the MRAC/PGE is 4.6-fold higher than that of the bare PGE. Using amperometric method, the anodic current is linear with AA concentration in the range of 0.5–2000_M, with a detection limit about 0.3_M. Furthermore, the proposed electrode can also avoid major interferences such as dopamine, uric acid, urea, and so on. This new method has been successfully applied for AA assay in urine and pharmaceutical preparations. |
| 学科主题 | 分析化学与药物化学 |
| 收录类别 | SCI |
| 资助信息 | National Nature Science Foundation of China (No. 20672121) |
| 语种 | 英语 |
| WOS记录号 | WOS:000275985700028 |
| 公开日期 | 2012-09-29 |
| 源URL | [http://210.77.64.217/handle/362003/1213]  |
| 专题 | 兰州化学物理研究所_中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 |
| 通讯作者 | Shao SJ(邵士俊); Shao SJ(邵士俊) |
| 推荐引用方式 GB/T 7714 | Shao SJ,Shao SJ,Guo Y. A highly selective amperometric sensor for ascorbic acid based on mesopore-rich active carbon-modified pyrolytic graphite electrode[J]. Electrochimica Acta,2010,55:2799-2804. |
| APA | 邵士俊,邵士俊,&郭勇.(2010).A highly selective amperometric sensor for ascorbic acid based on mesopore-rich active carbon-modified pyrolytic graphite electrode.Electrochimica Acta,55,2799-2804. |
| MLA | 邵士俊,et al."A highly selective amperometric sensor for ascorbic acid based on mesopore-rich active carbon-modified pyrolytic graphite electrode".Electrochimica Acta 55(2010):2799-2804. |
入库方式： OAI收割
来源：兰州化学物理研究所
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