ESR studies on a Friedel-Crafts alkylation reaction in [bmim]Cl-AlCl3 ionic liquid
文献类型：期刊论文
| 作者 | Liu WM(刘维民)
|
| 刊名 | Journal of the Chinese Chemical Society
 |
| 出版日期 | 2006 |
| 卷号 | 53期号:4页码:887-890 |
| 关键词 | ESR Cation radical Ionic liquids Friedel-Crafts alkylation |
| ISSN号 | 0009-4536 |
| 通讯作者 | 汪汉卿 |
| 中文摘要 | The paramagnetic complexes formed in Friedel-Crafts alkylation reaction systems are invistigated by electron spin resonance (ESR) spectroscopy, in room temperature ionic liquids system 1-butyl-3-methyllimidazolium chloride-aluminium chloride ([bmim]Cl-AlCl3). The results indicate that ESR spectra observed are due to polycyclic aromatic radical cations formed from their parent hydrocarbons. ESR spectrum of spin adduct is obtained in an ionic liquid system composed of [bmim]Cl-AlCl3. In acidic solution the 14N hyperfine coupling constant of 4-oxo-TEMPO, 2.15 mT, is appreciably larger due to an adduct formed with AlCl3. |
| 学科主题 | 分析化学与药物化学 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000240278300018 |
| 公开日期 | 2012-10-14 |
| 源URL | [http://210.77.64.217/handle/362003/1465]  |
| 专题 | 兰州化学物理研究所_中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 兰州化学物理研究所_固体润滑国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Liu WM. ESR studies on a Friedel-Crafts alkylation reaction in [bmim]Cl-AlCl3 ionic liquid[J]. Journal of the Chinese Chemical Society,2006,53(4):887-890. |
| APA | 刘维民.(2006).ESR studies on a Friedel-Crafts alkylation reaction in [bmim]Cl-AlCl3 ionic liquid.Journal of the Chinese Chemical Society,53(4),887-890. |
| MLA | 刘维民."ESR studies on a Friedel-Crafts alkylation reaction in [bmim]Cl-AlCl3 ionic liquid".Journal of the Chinese Chemical Society 53.4(2006):887-890. |
入库方式： OAI收割
来源：兰州化学物理研究所
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