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Conversion of fructose into 5-hydroxymethylfurfural (HMF) and its derivatives promoted by inorganic salt in alcohol

文献类型：期刊论文

作者Liu, Jitian1,2; Tang, Yu1,3; Wu, Kaigui2; Bi, Caifeng2; Cui, Qiu1
刊名CARBOHYDRATE RESEARCH
出版日期2012-03-01
卷号350期号:1页码:20-24
关键词Fructose HMF EMF Inorganic salt Alcohol
中文摘要The conversion of d-fructose to 5-hydroxymethylfurfural (HMF) on a 1 mmol scale was achieved in good yield (68%) using NH4Cl as catalyst in isopropanol at 120 °C. About 3% of 5-i-propoxymethylfurfural was formed. The reaction in ethanol at 100 °C on a 10 g scale gave a total yield of HMF and 5-ethoxymethylfurfural of 42%. No mineral acid such as H2SO4 and HCl are required.
英文摘要The conversion of D-fructose to 5-hydroxymethylfurfural (HMF) on a 1 mmol scale was achieved in good yield (68%) using NH4Cl as catalyst in isopropanol at 120 degrees C. About 3% of 5-i-propoxymethylfurfural was formed. The reaction in ethanol at 100 degrees C on a 10 g scale gave a total yield of HMF and 5-ethoxymethylfurfural of 42%. No mineral acid such as H2SO4 and HCl are required. (C) 2012 Elsevier Ltd. All rights reserved.
WOS标题词Science & Technology ; Life Sciences & Biomedicine ; Physical Sciences
学科主题代谢物组学
类目[WOS]Biochemistry & Molecular Biology ; Chemistry, Applied ; Chemistry, Organic
研究领域[WOS]Biochemistry & Molecular Biology ; Chemistry
关键词[WOS]IONIC LIQUIDS ; SELECTIVE DEHYDRATION ; CATALYZED CONVERSION ; SOLID ACID ; BIOMASS ; GLUCOSE ; EFFICIENT ; FUELS ; HYDROGENATION ; SUGARS
收录类别SCI ; CCR
语种英语
WOS记录号WOS:000301127400003
公开日期2012-11-11
源URL[http://ir.qibebt.ac.cn:8080/handle/337004/1226]  
专题青岛生物能源与过程研究所_代谢物组学团队
作者单位1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Energy Genet, Qingdao 266101, Peoples R China
2.Ocean Univ China, Coll Chem & Chem Engn, Qingdao 266101, Peoples R China
3.Tianjin Univ, Sch Pharmaceut Sci & Technol, Tianjin Key Lab Modern Drug Delivery & High Effic, Tianjin 300072, Peoples R China
推荐引用方式
GB/T 7714		 Liu, Jitian,Tang, Yu,Wu, Kaigui,et al. Conversion of fructose into 5-hydroxymethylfurfural (HMF) and its derivatives promoted by inorganic salt in alcohol[J]. CARBOHYDRATE RESEARCH,2012,350(1):20-24.
APA Liu, Jitian,Tang, Yu,Wu, Kaigui,Bi, Caifeng,&Cui, Qiu.(2012).Conversion of fructose into 5-hydroxymethylfurfural (HMF) and its derivatives promoted by inorganic salt in alcohol.CARBOHYDRATE RESEARCH,350(1),20-24.
MLA Liu, Jitian,et al."Conversion of fructose into 5-hydroxymethylfurfural (HMF) and its derivatives promoted by inorganic salt in alcohol".CARBOHYDRATE RESEARCH 350.1(2012):20-24.

入库方式： OAI收割

来源：青岛生物能源与过程研究所

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