Hierarchical micro/nano-structured titanium nitride spheres as a high-performance counter electrode for a dye-sensitized solar cell
文献类型：期刊论文
| 作者 | Zhang, Xiaoying1,2; Chen, Xiao1; Dong, Shanmu1,2; Liu, Zhihong1; Zhou, Xinhong3; Yao, Jianhua1; Pang, Shuping1; Xu, Hongxia1; Zhang, Zhongyi1,2; Li, Lanfeng1,3 |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY
 |
| 出版日期 | 2012 |
| 卷号 | 22期号:13页码:6067-6071 |
| 中文摘要 | Hierarchical micro/nano-structured TiN spheres (micro/nano-TiNs) counter electrodes are fabricated by coating hierarchical micro/nano-TiO2 paste onto Ti foil followed by a nitridation reaction. Compared with particulate TiN and TiN flat electrodes, the as-prepared hierarchical micro/nano-TiNs electrode based dye-sensitized solar cells (DSCs) delivers significantly improved photovoltaic performances due to the presence of the hierarchical structure. In particular, VOC is enhanced by about 60 mV, which may be predominantly attributed to the gaining of favourable interfacial active sites and the traces of N-doped carbon residues. After an initial optimization of the particle sizes of the hierarchical micro/nano-TiNs, the reflectance effect of large submicroscale particles is attempted to improve the ISC. The highest overall conversion efficiency yields 7.83%, which is 30% higher than that of Pt/FTO (6.04%). |
| 英文摘要 | Hierarchical micro/nano-structured TiN spheres (micro/nano-TiNs) counter electrodes are fabricated by coating hierarchical micro/nano-TiO2 paste onto Ti foil followed by a nitridation reaction. Compared with particulate TiN and TiN flat electrodes, the as-prepared hierarchical micro/nano-TiNs electrode based dye-sensitized solar cells (DSCs) delivers significantly improved photovoltaic performances due to the presence of the hierarchical structure. In particular, V-OC is enhanced by about 60 mV, which may be predominantly attributed to the gaining of favourable interfacial active sites and the traces of N-doped carbon residues. After an initial optimization of the particle sizes of the hierarchical micro/nano-TiNs, the reflectance effect of large submicroscale particles is attempted to improve the I-SC. The highest overall conversion efficiency yields 7.83%, which is 30% higher than that of Pt/FTO (6.04%). |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 学科主题 | 仿生能源系统 |
| 类目[WOS] | Chemistry, Physical ; Materials Science, Multidisciplinary |
| 研究领域[WOS] | Chemistry ; Materials Science |
| 关键词[WOS] | CARBON NANOTUBES ; CHARGE-TRANSPORT ; TIO2 FILMS ; LOW-COST ; EFFICIENT ; GRAPHENE ; CARBIDES ; SYSTEMS ; ION |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000301195300026 |
| 公开日期 | 2012-11-10 |
| 源URL | [http://ir.qibebt.ac.cn:8080/handle/337004/1162]  |
| 专题 | 青岛生物能源与过程研究所_仿生能源与储能系统团队 |
| 作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China 3.Qingdao Univ Sci & Technol, Qingdao 266101, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Xiaoying,Chen, Xiao,Dong, Shanmu,et al. Hierarchical micro/nano-structured titanium nitride spheres as a high-performance counter electrode for a dye-sensitized solar cell[J]. JOURNAL OF MATERIALS CHEMISTRY,2012,22(13):6067-6071. |
| APA | Zhang, Xiaoying.,Chen, Xiao.,Dong, Shanmu.,Liu, Zhihong.,Zhou, Xinhong.,...&Cui, Guanglei.(2012).Hierarchical micro/nano-structured titanium nitride spheres as a high-performance counter electrode for a dye-sensitized solar cell.JOURNAL OF MATERIALS CHEMISTRY,22(13),6067-6071. |
| MLA | Zhang, Xiaoying,et al."Hierarchical micro/nano-structured titanium nitride spheres as a high-performance counter electrode for a dye-sensitized solar cell".JOURNAL OF MATERIALS CHEMISTRY 22.13(2012):6067-6071. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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