Selective dehydration of fructose to 5-hydroxymethylfurfural catalyzed by mesoporous SBA-15-SO3H in ionic liquid BmimCl
文献类型：期刊论文
| 作者 | Guo, Xingcui; Cao, Quan; Jiang, Yijun; Guan, Jing; Wang, Xiaoyan; Mu, Xindong
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| 刊名 | CARBOHYDRATE RESEARCH
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| 出版日期 | 2012-04-01 |
| 卷号 | 351期号:3页码:35-41 |
| 关键词 | 5-Hydroxymethylfurfural (HMF) Fructose Dehydration Acid catalysts Ionic liquids |
| 中文摘要 | Mesoporous SBA-15 materials functionalized with propylsulfonic acid groups (SBA-15-SO(3)H) were synthesized through a conventional one-pot route. It was used as a catalyst for the selective synthesis of 5-hydroxymethylfurfural (HMF) from the dehydration of fructose using BmimCl as solvent. Reaction time, temperature and fructose concentration were investigated during the HMF synthesis procedure. The catalyst SBA-15-SO(3)H exhibits high fructose conversion (near 100%) and HMF selectivity (about 81%) with good stability in the HMF synthesis. It was a suitable catalyst to produce HMF from renewable carbohydrates in potential industrial process. |
| 英文摘要 | Mesoporous SBA-15 materials functionalized with propylsulfonic acid groups (SBA-15-SO3H) were synthesized through a conventional one-pot route. It was used as a catalyst for the selective synthesis of 5-hydroxymethylfurfural (HMF) from dehydration of fructose using BmimCl as solvent. Reaction time, temperature and fructose concentration were investigated during the HMF synthesis procedure. The catalyst SBA-15-SO3H exhibits high fructose conversion (near 100%) and HMF selectivity (about 81%) with good stability in the HMF synthesis. It was a suitable catalyst to produce HMF from renewable carbohydrates in potential industrial process. (C) 2012 Elsevier Ltd. All rights reserved. |
| 学科主题 | 绿色化学催化 |
| WOS标题词 | Science & Technology ; Life Sciences & Biomedicine ; Physical Sciences |
| 类目[WOS] | Biochemistry & Molecular Biology ; Chemistry, Applied ; Chemistry, Organic |
| 研究领域[WOS] | Biochemistry & Molecular Biology ; Chemistry |
| 关键词[WOS] | SULFONIC-ACID GROUPS ; EXCHANGE-RESIN ; ONE-POT ; CONVERSION ; EFFICIENT ; BIOMASS ; SILICA ; CHEMICALS ; SUCROSE ; SOLVENT |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000301128300004 |
| 公开日期 | 2012-11-16 |
| 源URL | [http://ir.qibebt.ac.cn:8080/handle/337004/1396]  |
| 专题 | 青岛生物能源与过程研究所_绿色化学催化团队 |
| 作者单位 | Chinese Acad Sci, Key Lab Biofuels, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guo, Xingcui,Cao, Quan,Jiang, Yijun,et al. Selective dehydration of fructose to 5-hydroxymethylfurfural catalyzed by mesoporous SBA-15-SO3H in ionic liquid BmimCl[J]. CARBOHYDRATE RESEARCH,2012,351(3):35-41. |
| APA | Guo, Xingcui,Cao, Quan,Jiang, Yijun,Guan, Jing,Wang, Xiaoyan,&Mu, Xindong.(2012).Selective dehydration of fructose to 5-hydroxymethylfurfural catalyzed by mesoporous SBA-15-SO3H in ionic liquid BmimCl.CARBOHYDRATE RESEARCH,351(3),35-41. |
| MLA | Guo, Xingcui,et al."Selective dehydration of fructose to 5-hydroxymethylfurfural catalyzed by mesoporous SBA-15-SO3H in ionic liquid BmimCl".CARBOHYDRATE RESEARCH 351.3(2012):35-41. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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