N-Heterocyclic carbene catalyzed intramolecular nucleophilic addition of carbonyl anion equivalents to enol ethers
文献类型：期刊论文
| 作者 | He JM(何金梅) ; Tang SC(唐寿初) ; Liu J(刘剑) ; Su YP(苏瀛鹏) ; Pan XF(潘鑫复) ; She XG(厍学功) |
| 刊名 | Tetrahedron
 |
| 出版日期 | 2008 |
| 卷号 | 64页码:8797-8800 |
| ISSN号 | 0040-4020 |
| 通讯作者 | 厍学功 |
| 中文摘要 | The intramolecular nucleophilic addition reaction of acyl anion equivalents to enol ethers is described, which was catalyzed by N-heterocyclic carbenes generated in situ from readily available thiazolium salt. In this transformation, benzofuranones were obtained in excellent yield. In combination with our previous work, the precise mechanistic elucidation for the formation of benzofuranones has been further investigated. A labeling experiment implied that the transformation proceeds through a nucleophilic addition mechanism. |
| 学科主题 | 物理化学 |
| 收录类别 | SCI |
| 资助信息 | the Special Doctorial Program Funds of the Ministry of Education of China (20040730008);NSFC (QT program, No. 20572037);NCET-05-0879;the key grant project of Chinese ministry of Education (No. 105169);and Gansu Science Foundation (3ZS051-A25-004) |
| 语种 | 英语 |
| WOS记录号 | WOS:000258841100029 |
| 公开日期 | 2012-11-09 |
| 源URL | [http://210.77.64.217/handle/362003/1914]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 推荐引用方式 GB/T 7714 | He JM,Tang SC,Liu J,et al. N-Heterocyclic carbene catalyzed intramolecular nucleophilic addition of carbonyl anion equivalents to enol ethers[J]. Tetrahedron,2008,64:8797-8800. |
| APA | 何金梅,唐寿初,刘剑,苏瀛鹏,潘鑫复,&厍学功.(2008).N-Heterocyclic carbene catalyzed intramolecular nucleophilic addition of carbonyl anion equivalents to enol ethers.Tetrahedron,64,8797-8800. |
| MLA | 何金梅,et al."N-Heterocyclic carbene catalyzed intramolecular nucleophilic addition of carbonyl anion equivalents to enol ethers".Tetrahedron 64(2008):8797-8800. |
入库方式： OAI收割
来源：兰州化学物理研究所
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