Schiff-base amino alcohol-zinc complex for enantioselective addition of phenylacetylene to aromatic ketones
文献类型：期刊论文
| 作者 | Chen C(陈超) ; Hong L(洪亮) ; Wang Q(王全) ; Zhang BZ(张邦治) ; Wang R(王锐) |
| 刊名 | Chem. Res. Chinese Universities
 |
| 出版日期 | 2008 |
| 卷号 | 24期号:3页码:306-311 |
| 关键词 | Chiral tertiary alcohol Lewis acid Ketone Schiff-base amino alcohol Sulfonamide alcohol Diol ligand |
| ISSN号 | 1005-9040 |
| 通讯作者 | 王锐 |
| 中文摘要 | A complete study of the asymmetric addition of phenylacetylene to ketones catalyzed by Schiff-base amino alcohol-Zn complex is reported in this article. The Schiff-base amino alcohols were easily prepared from amino acids in three steps. When the amount of ligand was I%(molar fraction), an e.e. value up to 94% was obtained. A series of practical chiral ligands were applied in the enantioselective addition of phenylacetylene to ketones without adding another stronger Lewis acid except zinc. |
| 学科主题 | 物理化学 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China(Nos.20472026;20525206);Chang Jiang Scholar Program of the Ministry of Education, China |
| 语种 | 英语 |
| WOS记录号 | WOS:000257176100014 |
| 公开日期 | 2012-11-09 |
| 源URL | [http://210.77.64.217/handle/362003/1932]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Chen C,Hong L,Wang Q,et al. Schiff-base amino alcohol-zinc complex for enantioselective addition of phenylacetylene to aromatic ketones[J]. Chem. Res. Chinese Universities,2008,24(3):306-311. |
| APA | 陈超,洪亮,王全,张邦治,&王锐.(2008).Schiff-base amino alcohol-zinc complex for enantioselective addition of phenylacetylene to aromatic ketones.Chem. Res. Chinese Universities,24(3),306-311. |
| MLA | 陈超,et al."Schiff-base amino alcohol-zinc complex for enantioselective addition of phenylacetylene to aromatic ketones".Chem. Res. Chinese Universities 24.3(2008):306-311. |
入库方式： OAI收割
来源：兰州化学物理研究所
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