Supramolecular assemblies formed by cooperative metal coordination and dimerization of the N-(2-pyirimidyl)-N´-(3-pyridyl)urea ligand via hydrogen bonding
文献类型：期刊论文
| 作者 | Huang XJ(黄晓卷) ; Yang XJ(杨晓娟); Yang XJ(杨晓娟)
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| 刊名 | Zeitschrift Fur Anorganische Und Allgemeine Chemie
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| 出版日期 | 2008 |
| 卷号 | 634页码:1210-1214 |
| 关键词 | N-(2-Pyrimidyl)-N -(3-pyridyl)urea Supramolecular structure Hydrogen bonding Cobalt Zinc |
| ISSN号 | 0044-2313 |
| 通讯作者 | 吴彪 ; 杨晓娟 |
| 中文摘要 | The supramolecular structures of two metal complexes, [CoCl2L2] (1) and [ZnCl2L2] (2), where L＝N-(2-pyrimidyl)-N-(3-pyridyl)urea, are reported. The complexes feature zigzag chains formed by the self-dimerization of the ligand via a pair of Nurea H···Npyrimidyl hydrogen bonds with the R22(8) motif. Only the pyridyl nitrogen atom coordinates to the metal atom whereas the two pyrimidyl N donors are involved in intra- and intermolecular hydrogen bonding interactions. The coordinated Cl atoms do not form any hydrogen bonds with the urea NH groups. The dimerization of the ligand (K＝90 M-1) was investigated by 1H NMR spectroscopy. |
| 学科主题 | 金属有机与超分子催化 |
| 收录类别 | SCI |
| 资助信息 | the “Bairen Jihua” project of Chinese Academy of Sciences |
| 语种 | 英语 |
| 公开日期 | 2012-11-09 |
| 源URL | [http://210.77.64.217/handle/362003/1952]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 兰州化学物理研究所_ERC国家工程研究中心 |
| 通讯作者 | Yang XJ(杨晓娟); Yang XJ(杨晓娟) |
| 推荐引用方式 GB/T 7714 | Huang XJ,Yang XJ,Yang XJ. Supramolecular assemblies formed by cooperative metal coordination and dimerization of the N-(2-pyirimidyl)-N´-(3-pyridyl)urea ligand via hydrogen bonding[J]. Zeitschrift Fur Anorganische Und Allgemeine Chemie,2008,634:1210-1214. |
| APA | 黄晓卷,杨晓娟,&杨晓娟.(2008).Supramolecular assemblies formed by cooperative metal coordination and dimerization of the N-(2-pyirimidyl)-N´-(3-pyridyl)urea ligand via hydrogen bonding.Zeitschrift Fur Anorganische Und Allgemeine Chemie,634,1210-1214. |
| MLA | 黄晓卷,et al."Supramolecular assemblies formed by cooperative metal coordination and dimerization of the N-(2-pyirimidyl)-N´-(3-pyridyl)urea ligand via hydrogen bonding".Zeitschrift Fur Anorganische Und Allgemeine Chemie 634(2008):1210-1214. |
入库方式： OAI收割
来源：兰州化学物理研究所
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