Synthesis, crystal structure, and enantioseparation of a homometallic, chiral cluster [Ru3(CO)9{1,2-μ-FcC(CH3) = NNC(S)NHCH3}]
文献类型：期刊论文
| 作者 | Xia CG(夏春谷) ; Xia CG(夏春谷); Hu B(胡斌)
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| 刊名 | JOURNAL OF CHEMICAL RESEARCH
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| 出版日期 | 2008 |
| 页码 | 322-323 |
| 关键词 | homometallic chiral cluster enantioseparation acetylferrocenyl-thiosemicarbazone X-ray structure |
| ISSN号 | 0308-2342 |
| 通讯作者 | 夏春谷 |
| 中文摘要 | Reaction of Ru3(CO)12 with the thio-Schiff base ligand acetylferrocenyl-thiosemicarbazone provides a one-step synthesis of the chiral cluster [Ru3(CO)9{1,2-μ-FcC(CH3) = NNC(S)NHCH3}] as a racemic mixture. One molecule of thiosemicarbazone was consumed in the cluster formation process, in which the ligand was deprotonated and acted as a bidentate N, S donor as well as bridging. The title cluster has been characterised by NMR, IR, HPLC and an X-ray structure determination. |
| 学科主题 | 清洁催化与生物转化 |
| 收录类别 | SCI |
| 资助信息 | the National Science Fund for Distinguished Young Scholars of China (No. 20625308) |
| 语种 | 英语 |
| 公开日期 | 2012-11-09 |
| 源URL | [http://210.77.64.217/handle/362003/1961]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 通讯作者 | Xia CG(夏春谷); Xia CG(夏春谷) |
| 推荐引用方式 GB/T 7714 | Xia CG,Xia CG,Hu B. Synthesis, crystal structure, and enantioseparation of a homometallic, chiral cluster [Ru3(CO)9{1,2-μ-FcC(CH3) = NNC(S)NHCH3}][J]. JOURNAL OF CHEMICAL RESEARCH,2008:322-323. |
| APA | 夏春谷,夏春谷,&胡斌.(2008).Synthesis, crystal structure, and enantioseparation of a homometallic, chiral cluster [Ru3(CO)9{1,2-μ-FcC(CH3) = NNC(S)NHCH3}].JOURNAL OF CHEMICAL RESEARCH,322-323. |
| MLA | 夏春谷,et al."Synthesis, crystal structure, and enantioseparation of a homometallic, chiral cluster [Ru3(CO)9{1,2-μ-FcC(CH3) = NNC(S)NHCH3}]".JOURNAL OF CHEMICAL RESEARCH (2008):322-323. |
入库方式： OAI收割
来源：兰州化学物理研究所
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