A simple and efficient recyclable phosphine-free catalytic system for alkoxycarbonylation and carbonylative Sonogashira coupling reactions of aryl iodides
文献类型：期刊论文
| 作者 | Chen J(陈静) ; Liu JH(刘建华); Xia CG(夏春谷)
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| 刊名 | Journal of Catalysis
 |
| 出版日期 | 2008 |
| 卷号 | 253页码:50-56 |
| 关键词 | Palladium on charcoal Alkoxycarbonylation Carbonylative Sonogashira coupling Aryl iodides Aryl esters α Recycle β-Alkynyl ketones |
| ISSN号 | 0021-9517 |
| 通讯作者 | 夏春谷 ; 陈静 |
| 中文摘要 | Using palladium on charcoal (Pd/C) and triethylamine as a novel, efficient, versatile, recyclable, and phosphine-free catalytic system, we carried out the alkoxycarbonylation of aryl iodides (alcohols or phenols as nucleophiles) and the carbonylative Sonogashira coupling reaction of aryl iodides with terminal alkynes, affording the corresponding aryl esters and α,β-alkynyl ketones in good to excellent yields under mild conditions. We found that both electron-withdrawing and electron-donating substituents on phenol enhanced the phenoxycarbonylation of iodobenzene. The recyclability of Pd/C was also demonstrated. |
| 学科主题 | 清洁催化与生物转化 ; 分子催化与技术 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Fund for Distinguished Young Scholars (No. 20625308) |
| 语种 | 英语 |
| WOS记录号 | WOS:000257176900006 |
| 公开日期 | 2012-11-09 |
| 源URL | [http://210.77.64.217/handle/362003/1964]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 通讯作者 | Chen J(陈静); Xia CG(夏春谷) |
| 推荐引用方式 GB/T 7714 | Chen J,Liu JH,Xia CG. A simple and efficient recyclable phosphine-free catalytic system for alkoxycarbonylation and carbonylative Sonogashira coupling reactions of aryl iodides[J]. Journal of Catalysis,2008,253:50-56. |
| APA | 陈静,刘建华,&夏春谷.(2008).A simple and efficient recyclable phosphine-free catalytic system for alkoxycarbonylation and carbonylative Sonogashira coupling reactions of aryl iodides.Journal of Catalysis,253,50-56. |
| MLA | 陈静,et al."A simple and efficient recyclable phosphine-free catalytic system for alkoxycarbonylation and carbonylative Sonogashira coupling reactions of aryl iodides".Journal of Catalysis 253(2008):50-56. |
入库方式： OAI收割
来源：兰州化学物理研究所
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