Ferrocene-based bidentate phosphonite ligands for rhodium(I)-catalyzed enantioselective hydroformylation
文献类型：期刊论文
| 作者 | Xia CG(夏春谷)
|
| 刊名 | Tetrahedron Letters
 |
| 出版日期 | 2008 |
| 卷号 | 49页码:4862-4864 |
| 关键词 | Asymmetric catalysis Hydroformylation Bidentate ligand Phosphonite Rhodium |
| ISSN号 | 0040-4039 |
| 通讯作者 | 夏春谷 ; 丁奎岭 |
| 中文摘要 | A new class of chiral modular bidentate phosphonite ligands has been synthesized in good overall yields by using cheap trans-1,2-diaminocyclohexane and ferrocene as starting materials, and applied in the Rh(I)-catalyzed asymmetric hydroformylation of vinyl acetate and styrene to afford the corresponding optically active aldehydes with good regioselectivity (up to 16.9 b/l ratio) and moderate to good enantioselectivity (up to 83% ee). The substituents on the backbone of the ligands are found to exhibit a remarkable effect on both the regio- and enantioselectivity of the catalysis. |
| 学科主题 | 清洁催化与生物转化 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (Nos. 20532050;20423001);the Chinese Academy of Sciences;the Major Basic Research Development Program of China (Grant No. 2006CB806106) |
| 语种 | 英语 |
| WOS记录号 | WOS:000258274200013 |
| 公开日期 | 2012-11-09 |
| 源URL | [http://210.77.64.217/handle/362003/1967]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 通讯作者 | Xia CG(夏春谷) |
| 推荐引用方式 GB/T 7714 | Xia CG. Ferrocene-based bidentate phosphonite ligands for rhodium(I)-catalyzed enantioselective hydroformylation[J]. Tetrahedron Letters,2008,49:4862-4864. |
| APA | 夏春谷.(2008).Ferrocene-based bidentate phosphonite ligands for rhodium(I)-catalyzed enantioselective hydroformylation.Tetrahedron Letters,49,4862-4864. |
| MLA | 夏春谷."Ferrocene-based bidentate phosphonite ligands for rhodium(I)-catalyzed enantioselective hydroformylation".Tetrahedron Letters 49(2008):4862-4864. |
入库方式： OAI收割
来源：兰州化学物理研究所
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