Effective oxidation of alcohols to aldehydes with hydrogen peroxide catalyzed by Pd (OAc)2/SO under solvent-free conditions
文献类型：期刊论文
| 作者 | Sun KP(孙鲲鹏)
|
| 刊名 | Catalysis Communications
 |
| 出版日期 | 2008 |
| 卷号 | 9页码:386-390 |
| 关键词 | Alcohols Aldehydes Hydrogen peroxide Oxidation Palladium Sodium oxalate |
| ISSN号 | 1566-7367 |
| 通讯作者 | 徐贤伦 |
| 中文摘要 | With oxygen that was supplied by hydrogen peroxide as oxidant, secondary and primary aliphatic alcohols, primary allylic alcohols could be efficiently oxidized to aldehydes or ketones in high yields in the presence of Pd (OAc)2 sodium oxalate (SO) under solvent-free conditions, it is a high yielding and operationally simple method. Acetic acid is testified to attend the reaction, the acetate ligands are environed to serve two purposes: as a ligand for the PdII center and as a base to deprotonate the Pd-bound alcohol, but acetic acid has not shown in previous bidentate ligands systems, so a mechanism is proposed on the basis of the mechanisms reported by the pioneers. |
| 学科主题 | 物理化学 |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2012-11-09 |
| 源URL | [http://210.77.64.217/handle/362003/1986]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 兰州化学物理研究所_绿色化学研究发展中心 |
| 推荐引用方式 GB/T 7714 | Sun KP. Effective oxidation of alcohols to aldehydes with hydrogen peroxide catalyzed by Pd (OAc)2/SO under solvent-free conditions[J]. Catalysis Communications,2008,9:386-390. |
| APA | 孙鲲鹏.(2008).Effective oxidation of alcohols to aldehydes with hydrogen peroxide catalyzed by Pd (OAc)2/SO under solvent-free conditions.Catalysis Communications,9,386-390. |
| MLA | 孙鲲鹏."Effective oxidation of alcohols to aldehydes with hydrogen peroxide catalyzed by Pd (OAc)2/SO under solvent-free conditions".Catalysis Communications 9(2008):386-390. |
入库方式： OAI收割
来源：兰州化学物理研究所
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