Research on some novel functional azobenzene derivatives with alkyl chains and different substituted groups
文献类型：期刊论文
| 作者 | Jiao TF(焦体峰) ; Li XH(李旭辉) ; Zhou JX(周靖欣) ; Xing YY(邢媛媛) ; Ren J(任静) |
| 刊名 | Key Engineering Materials
 |
| 出版日期 | 2011 |
| 卷号 | 474-476页码:537-542 |
| 关键词 | Azobenzene Functional material Substituted groups Spectral measurement Thermal analysis |
| ISSN号 | 1662-9795 |
| 通讯作者 | 焦体峰 |
| 中文摘要 | Two functional azobenzene derivatives with alkyl chains and different substituted groups have been synthesized and their photoisomerization have also been investigated. It has been found that depending on the alkyl chain and different substituted groups, the formed azobenzene derivatives showed different properties, indicating distinct regulation of molecular skeletons. UV and IR data confirmed commonly the characteristic absorption of alkyl chain and aromatic segments in molecular structures. Thermal analysis demonstrated that the structural influence of both compounds in different temperature ranges. The difference of thermal stability is mainly attributed to the formation of Schiff base group and different substituent groups in molecular structure. The photoisomerization of these compounds both in solution and in cast film can undergo trans-to-cis isomerization by UV light irradiation, depending on different substituted groups. The present results have demonstrated that the special properties of azobenzene derivatives can be effectively turned by modifying molecular structures of objective compounds with proper substituted groups, which show potential application in functional material field. |
| 学科主题 | 材料科学与物理化学 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (NO.20903078);the Natural Science Foundation of Hebei Province (NO.B2009000347);Hundred Excellent Innovation Talents from Universities and Colleges of Hebei Province (NO.CPRC020);the Open Foundation of State Key Laboratory of Solid Lubrication (Lanzhou Institute of Chemical Physics;CAS)(NO.1002);the Scientific Research Plan of Education Department of Hebei Province (NO.Z2009146);the Scientific and Technological Research and Development Program of Qinhuangdao City (Nos. 201001A100;201001A101);the Doctoral Foundation of Yanshan University (NO.B360);J. Ren is thankful to the Undergraduate Innovational Experimentation Program of Yanshan University (NO.CXSYC1013) |
| 语种 | 英语 |
| 公开日期 | 2012-09-24 |
| 源URL | [http://210.77.64.217/handle/362003/773]  |
| 专题 | 兰州化学物理研究所_固体润滑国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Jiao TF,Li XH,Zhou JX,et al. Research on some novel functional azobenzene derivatives with alkyl chains and different substituted groups[J]. Key Engineering Materials,2011,474-476:537-542. |
| APA | 焦体峰,李旭辉,周靖欣,邢媛媛,&任静.(2011).Research on some novel functional azobenzene derivatives with alkyl chains and different substituted groups.Key Engineering Materials,474-476,537-542. |
| MLA | 焦体峰,et al."Research on some novel functional azobenzene derivatives with alkyl chains and different substituted groups".Key Engineering Materials 474-476(2011):537-542. |
入库方式： OAI收割
来源：兰州化学物理研究所
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