Spectral and thermal investigation of novel glycine-based schiff base derivative and its metal complexes
文献类型：期刊论文
| 作者 | Jiao TF(焦体峰) ; Zhou Y(周媛) ; Zhou JX(周靖欣) ; Xing YY(邢媛媛) ; Li YH(李阳辉) |
| 刊名 | Key Engineering Materials
 |
| 出版日期 | 2011 |
| 卷号 | 474-476页码:543-547 |
| 关键词 | Glyscine Schiff base Metal complex Ligand Thermal stability |
| ISSN号 | 1662-9795 |
| 通讯作者 | 焦体峰 |
| 中文摘要 | A novel glycine-based Schiff base derivative (abbreviated as C16GlySb) containing long alkyl chain was synthesized from glycine reacted with 4-cetyloxy-2-hydroxybenzaldehyde and sequentially coordinated with various metal ions to give the corresponding metal complexes (abbreviated as G-M). The products were characterized by UV-Vis spectra and FT-IR spectra. At the same time, the thermal stability was measured by TG-DTA instrument. FT-IR analysis indicated that the nitrogen atom in imino group, oxygen atom in phenolic hydroxyl group, and carboxylic ion participated in coordinating with transition metal ion in doubly-bridged mode. UV spectra showed that compared with ethanol solution, the cast film on quartz plate showed H-type or J-type aggregate structure. In addition, the thermal stability of G-M had been obviously superior to that of the ligand C16GlySb. The present results have showed potential application in fields of functional material and catalyst. |
| 学科主题 | 材料科学与物理化学 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (NO.20903078);the Natural Science Foundation of Hebei Province (NO.B2009000347);Hundred Excellent Innovation Talents from Universities and Colleges of Hebei Province (NO.CPRC020);the Open Foundation of State Key Laboratory of Solid Lubrication (Lanzhou Institute of Chemical Physics;CAS) (NO.1002);the Scientific Research Plan of Education Department of Hebei Province (NO.Z2009146);the Scientific and Technological Research and Development Program of Qinhuangdao City (Nos. 201001A100;201001A101);the Doctoral Foundation of Yanshan University (NO.B360) |
| 语种 | 英语 |
| 公开日期 | 2012-09-24 |
| 源URL | [http://210.77.64.217/handle/362003/774]  |
| 专题 | 兰州化学物理研究所_固体润滑国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Jiao TF,Zhou Y,Zhou JX,et al. Spectral and thermal investigation of novel glycine-based schiff base derivative and its metal complexes[J]. Key Engineering Materials,2011,474-476:543-547. |
| APA | 焦体峰,周媛,周靖欣,邢媛媛,&李阳辉.(2011).Spectral and thermal investigation of novel glycine-based schiff base derivative and its metal complexes.Key Engineering Materials,474-476,543-547. |
| MLA | 焦体峰,et al."Spectral and thermal investigation of novel glycine-based schiff base derivative and its metal complexes".Key Engineering Materials 474-476(2011):543-547. |
入库方式： OAI收割
来源：兰州化学物理研究所
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