Self-Assembly of Ionic Liquids and Metal Complexes in Super-Cages of NaY: Integration of Free Catalysts and Solvent Molecules into Confined Catalytic Sites
文献类型：期刊论文
| 作者 | Deng YQ(邓友全) ; He YD(何昱德); Lu LJ(卢六斤); Zhang QH(张庆华); Shi F(石峰); Shi F(石峰); Ma XY(马祥元)
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| 刊名 | Chinese Journal of Catalysis
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| 出版日期 | 2010 |
| 卷号 | 31期号:8页码:933-937 |
| 关键词 | active site ionic liquid metal complex carbonylation aniline phenyl methyl carbamate turnover frequency |
| ISSN号 | 0253-9837 |
| 通讯作者 | 邓友全 ; 石峰 |
| 中文摘要 | The integration of a free metal complex, Pd(phen)2+, and a room temperature ionic liquid (IL) solvent molecule, 1-decyl-3-methyl imidazolium bromide, into a complete catalytically active site and confined in a NaY zeolite super-cage with an appropriate spatial arrangement was investigated. This integration was achieved through a molecular self-assembly method. A preliminary test of this catalyst system for the carbonylation of aniline to methyl phenyl carbamate indicated that far higher catalytic activity could be achieved (TOF increased from 3 000 to 23 000 h–1) with far lower amounts of the IL solvent and the Pd complex in comparison with a simple mixture of Pd(phen)Cl2/IL/NaY as the catalyst. This new system can also be applied to other areas of catalysis. |
| 学科主题 | 物理化学 |
| 收录类别 | CSCD |
| 语种 | 英语 |
| CSCD记录号 | CSCD:3987731 |
| WOS记录号 | WOS:000282079400008 |
| 公开日期 | 2012-11-14 |
| 源URL | [http://210.77.64.217/handle/362003/2208]  |
| 专题 | 兰州化学物理研究所_绿色化学研究发展中心 |
| 通讯作者 | Deng YQ(邓友全); Shi F(石峰); Shi F(石峰) |
| 推荐引用方式 GB/T 7714 | Deng YQ,He YD,Lu LJ,et al. Self-Assembly of Ionic Liquids and Metal Complexes in Super-Cages of NaY: Integration of Free Catalysts and Solvent Molecules into Confined Catalytic Sites[J]. Chinese Journal of Catalysis,2010,31(8):933-937. |
| APA | 邓友全.,何昱德.,卢六斤.,张庆华.,石峰.,...&马祥元.(2010).Self-Assembly of Ionic Liquids and Metal Complexes in Super-Cages of NaY: Integration of Free Catalysts and Solvent Molecules into Confined Catalytic Sites.Chinese Journal of Catalysis,31(8),933-937. |
| MLA | 邓友全,et al."Self-Assembly of Ionic Liquids and Metal Complexes in Super-Cages of NaY: Integration of Free Catalysts and Solvent Molecules into Confined Catalytic Sites".Chinese Journal of Catalysis 31.8(2010):933-937. |
入库方式： OAI收割
来源：兰州化学物理研究所
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