Sulfate binding in zinc(II) complexes of a monopyridylurea ligand N-(1-naphthyl)-N′-(3-pyridyl)urea
文献类型：期刊论文
| 作者 | Huang XJ(黄晓卷) ; Xia YN(夏娅娜); Yang XJ(杨晓娟)
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| 刊名 | Inorg. Chem. Commun.
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| 出版日期 | 2010 |
| 卷号 | 13页码:1103-1107 |
| 关键词 | Sulfate binding N-(1-naphthyl)-N′-(3-pyridyl)urea Hydrogen-bonded frameworks Fluorescence |
| ISSN号 | 1387-7003 |
| 通讯作者 | 吴彪 |
| 中文摘要 | Two zinc(II) complexes of a urea-functionalized pyridyl ligand, [Zn(SO4)L3]·CH3OH (1) and {[Zn(μ2-SO4)L2]·0.5CH3OH}n (2) (L=N-(1-naphthyl)-N′-(3-pyridyl)urea), have been synthesized by the reaction of L with ZnSO4·7H2O under different conditions. Complex 1 is a hydrogen-bonded 2D grid structure in which the sulfate anion not only coordinates to the ZnII ion as a monodentate ligand but also forms multiple hydrogen bonds with the urea groups of adjacent molecules. In complex 2 the sulfate ion serves as a μ2-bridging ligand, connecting the ZnII ions to form an infinite 1D organic–inorganic hybrid framework. Meanwhile, the sulfate anion is also bound by neighboring ligands through hydrogen bonds between urea groups and the noncoordinated oxygen atoms. The solid-state emission spectra of 1 and 2 show a red shift of the fluorescence emission of ligand L. |
| 学科主题 | 金属有机功能材料 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (Grant No. 20872149);the “Bairen Jihua” project of the Chinese Academy of Sciences |
| 语种 | 英语 |
| 公开日期 | 2012-11-30 |
| 源URL | [http://210.77.64.217/handle/362003/2284]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 兰州化学物理研究所_ERC国家工程研究中心 |
| 推荐引用方式 GB/T 7714 | Huang XJ,Xia YN,Yang XJ. Sulfate binding in zinc(II) complexes of a monopyridylurea ligand N-(1-naphthyl)-N′-(3-pyridyl)urea[J]. Inorg. Chem. Commun.,2010,13:1103-1107. |
| APA | 黄晓卷,夏娅娜,&杨晓娟.(2010).Sulfate binding in zinc(II) complexes of a monopyridylurea ligand N-(1-naphthyl)-N′-(3-pyridyl)urea.Inorg. Chem. Commun.,13,1103-1107. |
| MLA | 黄晓卷,et al."Sulfate binding in zinc(II) complexes of a monopyridylurea ligand N-(1-naphthyl)-N′-(3-pyridyl)urea".Inorg. Chem. Commun. 13(2010):1103-1107. |
入库方式： OAI收割
来源：兰州化学物理研究所
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