Anion binding of a bis(pyridylcarbamate) receptor bearing a diethylene glycol spacer
文献类型:期刊论文
作者 | Yang XJ(杨晓娟)![]() ![]() |
刊名 | Supramolecular Chemistry
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出版日期 | 2010 |
卷号 | 22期号:5页码:318-324 |
关键词 | anion receptor bis(pyridylcarbamate) hydrogen-bonded macrocycle |
ISSN号 | 1061-0278 |
通讯作者 | 吴彪 |
中文摘要 | A flexible bis(pyridylcarbamate) receptor, 3-pyridyl-carbamic-acid-oxydi-1,2-ethanediylester (L2) and the anion complexes (1–3) of the doubly protonated ligand ([L2H2]2þ) with ClO-4 , SO-24 and Cl2 are reported. The binding modes of [L2H2]2þ with the anions in 1–3 in the solid state are established by X-ray single crystal diffraction. Compounds 1 and 3 feature intriguing anionic polymer fashions. In compound 1, two zigzag perchlorate–water chains are encapsulated in the 1D channel constructed by 2þ2 (2[L2H2]2þ þ 2ClO-4 ) hydrogen-bonded macrocycles, while in 3 the chloride ions are trapped on the wall of the hydrogen-bonded 1D channel formed by two U-shaped ligands. For compound 2, the packing diagram displays a corrugated layer structure, with the sulphate ions and the water molecules located between the layers. Receptor L2 crystallises with perchlorate from the acid mixture HClO4, H2SO4 and HCl. |
学科主题 | 金属有机功能材料 |
收录类别 | SCI |
资助信息 | the National Natural Science Foundation of China (Grant No. 20872149);the “Bairen Jihua” project of Chinese Academy of Sciences |
语种 | 英语 |
WOS记录号 | WOS:000277752800005 |
公开日期 | 2012-11-30 |
源URL | [http://210.77.64.217/handle/362003/2285] ![]() |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 兰州化学物理研究所_ERC国家工程研究中心 |
推荐引用方式 GB/T 7714 | Yang XJ,Xia YN. Anion binding of a bis(pyridylcarbamate) receptor bearing a diethylene glycol spacer[J]. Supramolecular Chemistry,2010,22(5):318-324. |
APA | 杨晓娟,&夏娅娜.(2010).Anion binding of a bis(pyridylcarbamate) receptor bearing a diethylene glycol spacer.Supramolecular Chemistry,22(5),318-324. |
MLA | 杨晓娟,et al."Anion binding of a bis(pyridylcarbamate) receptor bearing a diethylene glycol spacer".Supramolecular Chemistry 22.5(2010):318-324. |
入库方式: OAI收割
来源:兰州化学物理研究所
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