中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Anion binding of a bis(pyridylcarbamate) receptor bearing a diethylene glycol spacer

文献类型:期刊论文

作者Yang XJ(杨晓娟); Xia YN(夏娅娜)
刊名Supramolecular Chemistry
出版日期2010
卷号22期号:5页码:318-324
关键词anion receptor bis(pyridylcarbamate) hydrogen-bonded macrocycle
ISSN号1061-0278
通讯作者吴彪
中文摘要A flexible bis(pyridylcarbamate) receptor, 3-pyridyl-carbamic-acid-oxydi-1,2-ethanediylester (L2) and the anion complexes (1–3) of the doubly protonated ligand ([L2H2]2þ) with ClO-4 , SO-24 and Cl2 are reported. The binding modes of [L2H2]2þ with the anions in 1–3 in the solid state are established by X-ray single crystal diffraction. Compounds 1 and 3 feature intriguing anionic polymer fashions. In compound 1, two zigzag perchlorate–water chains are encapsulated in the 1D channel constructed by 2þ2 (2[L2H2]2þ þ 2ClO-4 ) hydrogen-bonded macrocycles, while in 3 the chloride ions are trapped on the wall of the hydrogen-bonded 1D channel formed by two U-shaped ligands. For compound 2, the packing diagram displays a corrugated layer structure, with the sulphate ions and the water molecules located between the layers. Receptor L2 crystallises with perchlorate from the acid mixture HClO4, H2SO4 and HCl.
学科主题金属有机功能材料
收录类别SCI
资助信息the National Natural Science Foundation of China (Grant No. 20872149);the “Bairen Jihua” project of Chinese Academy of Sciences
语种英语
WOS记录号WOS:000277752800005
公开日期2012-11-30
源URL[http://210.77.64.217/handle/362003/2285]  
专题兰州化学物理研究所_OSSO国家重点实验室
兰州化学物理研究所_ERC国家工程研究中心
推荐引用方式
GB/T 7714
Yang XJ,Xia YN. Anion binding of a bis(pyridylcarbamate) receptor bearing a diethylene glycol spacer[J]. Supramolecular Chemistry,2010,22(5):318-324.
APA 杨晓娟,&夏娅娜.(2010).Anion binding of a bis(pyridylcarbamate) receptor bearing a diethylene glycol spacer.Supramolecular Chemistry,22(5),318-324.
MLA 杨晓娟,et al."Anion binding of a bis(pyridylcarbamate) receptor bearing a diethylene glycol spacer".Supramolecular Chemistry 22.5(2010):318-324.

入库方式: OAI收割

来源:兰州化学物理研究所

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