Skeletal isomerization of n-pentane over platinum-promoted tungstophosphoric acid supported on MCM-41
文献类型：期刊论文
| 作者 | Qi YX(齐彦兴) ; Lv GX(吕功煊); Lv GX(吕功煊)
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| 刊名 | Catalysis Letters
 |
| 出版日期 | 2008 |
| 卷号 | 125页码:83-89 |
| 关键词 | Skeletal isomerization n-Pentane Tungstophosphoric acid MCM-41 |
| ISSN号 | 1011-372X |
| 通讯作者 | 齐彦兴 ; 吕功煊 |
| 中文摘要 | Skeletal isomerization of n-pentane in the presence of hydrogen has been studied over Pt-promoted H3PW12O40 (TPA)/MCM-41 bifunctional catalyst. A series of solid acid catalysts with different loading amount of TPA and Pt were prepared and characterized by XRD, FT-IR and XPS. The optimal catalytic activity of Pt-TPA/MCM-41 was observed with 2% Pt and 30% TPA. According to the cracked products distribution, this is typical of a monomolecular bifunctional metal-acid mechanism. Further, catalysts with different combination of noble metals (Pt, Pd and Ru), heteropoly acids (HPAs) (TPA, tungstosilicic acid (TSA), and molybdophosphoric acid (MPA)) and supports (MCM-41, SBA-1 and SiO2) were also synthesized and their catalytic performances were compared. |
| 学科主题 | 环境催化与清洁能源 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000259189200013 |
| 公开日期 | 2012-12-03 |
| 源URL | [http://210.77.64.217/handle/362003/2347]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 兰州化学物理研究所_ERC国家工程研究中心 |
| 通讯作者 | Qi YX(齐彦兴); Lv GX(吕功煊); Lv GX(吕功煊) |
| 推荐引用方式 GB/T 7714 | Qi YX,Lv GX,Lv GX. Skeletal isomerization of n-pentane over platinum-promoted tungstophosphoric acid supported on MCM-41[J]. Catalysis Letters,2008,125:83-89. |
| APA | 齐彦兴,吕功煊,&吕功煊.(2008).Skeletal isomerization of n-pentane over platinum-promoted tungstophosphoric acid supported on MCM-41.Catalysis Letters,125,83-89. |
| MLA | 齐彦兴,et al."Skeletal isomerization of n-pentane over platinum-promoted tungstophosphoric acid supported on MCM-41".Catalysis Letters 125(2008):83-89. |
入库方式： OAI收割
来源：兰州化学物理研究所
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