A New Diiminopyridyl Cobalt Complex [CoCl2L] (L = 2,6-Bis(N,N’bis(2,6-diisopropyl-4-(2,3-dimethyoxylbenzoylamide)phenylimino))pyridine)
文献类型：期刊论文
| 作者 | Xia YN(夏娅娜)
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| 刊名 | Chinese J. Struct. Chem.
 |
| 出版日期 | 2010 |
| 卷号 | 29期号:6页码:869-874 |
| 关键词 | 2,6-bis(N,N΄-bis(2,6-diisopropyl-4-(2,3-dimethyoxylbenzoylamide)phenylimino)) pyridine cobalt crystal structure fluorescence |
| ISSN号 | 0254-5861 |
| 通讯作者 | 吴彪 |
| 中文摘要 | The reaction of CoCl2·6H2O with 2,6-bis(N,N΄-bis(2,6-diisopropyl-4-(2,3-dimethyoxyl-benzoylamide)phenylimino))pyridine (L) afforded the complex [CoCl2L], which was fully characterized by elemental analysis, UV-vis, IR spectroscopy, fluorescence, and X-ray diffraction analysis. The compound is of triclinic system, space group P1 with a = 13.058(3), b = 13.798(3), c =16.695(3) Å, α = 98.191(3), β = 102.792(3), γ = 101.820(3)°, V = 2815.0(9) Å3, Z = 2, F(000) = 1122, μ = 0.45 mm−1, R = 0.061 and wR = 0.1349 for 9842 observed reflections (I > 2σ(I)). The Co(II) center adopts a distorted square-pyramidal coordination geometry. The extended structure shows a one-dimensional zigzag double chain linked by hydrogen bonds and π-π stacking interactions. |
| 学科主题 | 金属有机功能材料 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (No. 20872149) |
| 语种 | 英语 |
| 公开日期 | 2012-11-30 |
| 源URL | [http://210.77.64.217/handle/362003/2286]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Xia YN. A New Diiminopyridyl Cobalt Complex [CoCl2L] (L = 2,6-Bis(N,N’bis(2,6-diisopropyl-4-(2,3-dimethyoxylbenzoylamide)phenylimino))pyridine)[J]. Chinese J. Struct. Chem.,2010,29(6):869-874. |
| APA | 夏娅娜.(2010).A New Diiminopyridyl Cobalt Complex [CoCl2L] (L = 2,6-Bis(N,N’bis(2,6-diisopropyl-4-(2,3-dimethyoxylbenzoylamide)phenylimino))pyridine).Chinese J. Struct. Chem.,29(6),869-874. |
| MLA | 夏娅娜."A New Diiminopyridyl Cobalt Complex [CoCl2L] (L = 2,6-Bis(N,N’bis(2,6-diisopropyl-4-(2,3-dimethyoxylbenzoylamide)phenylimino))pyridine)".Chinese J. Struct. Chem. 29.6(2010):869-874. |
入库方式： OAI收割
来源：兰州化学物理研究所
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