A Hydrogen-bonded Tubular Structure of Zinc(II) and Methyl-3-pyridylcarbamate
文献类型：期刊论文
| 作者 | Xia YN(夏娅娜)
|
| 刊名 | Chinese J. Struct. Chem.
 |
| 出版日期 | 2010 |
| 卷号 | 29期号:6页码:875-878 |
| 关键词 | zinc methyl-3-pyridylcarbamate hydrogen-bonded tubular structure |
| ISSN号 | 0254-5861 |
| 通讯作者 | 吴彪 |
| 中文摘要 | A zinc(II) compound [ZnCl2(mpcm)2] (1, mpcm = methyl-3-pyridylcarbamate) was prepared by solvothermal reaction and characterized by elemental analysis, IR spectroscopy, TGA and single-crystal X-ray diffraction. The crystal is of monoclinic system, space group P21/n, C14H16ZnCl2N4O4, Mr = 440.58, a = 8.7893(7), b = 24.978(2), c = 9.2510(8) Å, β = 109.318(1)°, V =1916.6(3) Å3, Z = 4, θ = 1.63～25.20°, Dc = 1.527 g/cm3, μ = 1.585 mm-1, F(000) = 896, the final R = 0.0255 and wR = 0.0654 for 3080 observed reflections with I > 2σ(I). The zinc atom is four-coordinated by the pyridyl groups of two mpcm ligands and two chloride ions with a tetrahedral geometry. Two [ZnCl2(mpcm)2] subunits are held together by a pair of hydrogen bonds, forming a 32-membered macrocyclic dimer, which is further extended into a 3D tubular structure via hydrogen bonding. |
| 学科主题 | 金属有机功能材料 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (No. 20872149) |
| 语种 | 英语 |
| WOS记录号 | WOS:000279582300007 |
| 公开日期 | 2012-11-30 |
| 源URL | [http://210.77.64.217/handle/362003/2287]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Xia YN. A Hydrogen-bonded Tubular Structure of Zinc(II) and Methyl-3-pyridylcarbamate[J]. Chinese J. Struct. Chem.,2010,29(6):875-878. |
| APA | 夏娅娜.(2010).A Hydrogen-bonded Tubular Structure of Zinc(II) and Methyl-3-pyridylcarbamate.Chinese J. Struct. Chem.,29(6),875-878. |
| MLA | 夏娅娜."A Hydrogen-bonded Tubular Structure of Zinc(II) and Methyl-3-pyridylcarbamate".Chinese J. Struct. Chem. 29.6(2010):875-878. |
入库方式： OAI收割
来源：兰州化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。