中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis of dialkyl hexamethylene-1,6-dicarbamate from 1,6-hexamethylenediamine and alkyl carbamate over FeCl3 as catalyst

文献类型:期刊论文

作者Deng YQ(邓友全); Shang JP(尚建鹏); Ma XY(马祥元); Cui XJ(崔新江); Shi F(石峰); Deng YQ(邓友全)
刊名Catalysis Communications
出版日期2009
卷号10页码:1248-1251
关键词Non-phosgene Carbamate Carbonylation 1,6-Hexamethylenediamine Isocyanate
ISSN号1566-7367
通讯作者邓友全
中文摘要A series of catalysts (e.g. FeCl3, Zn(OAc)2, Pb(NO3)2, etc.) were tested for the trans-esterification reaction of 1,6-hexamethylenediamine (HDA) with methyl carbamate (MC), ethyl carbamate (EC), and butyl car-bamate (BC) to afford dialkyl hexamethylene-1,6-dicarbamate (AHDC). By applying the optimized condi-tion, 100% conversion of HDA and 93% yield to diethyl hexamethylene-1,6-dicarbamate (EHDC) could be obtained using FeCl3 as catalyst. The desired products could be precipitated by adding water into the resulting mixture, and the activity of recovered catalyst could be maintained.
学科主题物理化学
收录类别SCI
语种英语
公开日期2012-12-01
源URL[http://210.77.64.217/handle/362003/2296]  
专题兰州化学物理研究所_绿色化学研究发展中心
兰州化学物理研究所_OSSO国家重点实验室
通讯作者Deng YQ(邓友全); Deng YQ(邓友全)
推荐引用方式
GB/T 7714
Deng YQ,Shang JP,Ma XY,et al. Synthesis of dialkyl hexamethylene-1,6-dicarbamate from 1,6-hexamethylenediamine and alkyl carbamate over FeCl3 as catalyst[J]. Catalysis Communications,2009,10:1248-1251.
APA 邓友全,尚建鹏,马祥元,崔新江,石峰,&邓友全.(2009).Synthesis of dialkyl hexamethylene-1,6-dicarbamate from 1,6-hexamethylenediamine and alkyl carbamate over FeCl3 as catalyst.Catalysis Communications,10,1248-1251.
MLA 邓友全,et al."Synthesis of dialkyl hexamethylene-1,6-dicarbamate from 1,6-hexamethylenediamine and alkyl carbamate over FeCl3 as catalyst".Catalysis Communications 10(2009):1248-1251.

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来源:兰州化学物理研究所

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