Synthesis of dialkyl hexamethylene-1,6-dicarbamate from 1,6-hexamethylenediamine and alkyl carbamate over FeCl3 as catalyst
文献类型：期刊论文
| 作者 | Deng YQ(邓友全) ; Shang JP(尚建鹏); Ma XY(马祥元); Cui XJ(崔新江); Shi F(石峰); Deng YQ(邓友全)
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| 刊名 | Catalysis Communications
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| 出版日期 | 2009 |
| 卷号 | 10页码:1248-1251 |
| 关键词 | Non-phosgene Carbamate Carbonylation 1,6-Hexamethylenediamine Isocyanate |
| ISSN号 | 1566-7367 |
| 通讯作者 | 邓友全 |
| 中文摘要 | A series of catalysts (e.g. FeCl3, Zn(OAc)2, Pb(NO3)2, etc.) were tested for the trans-esterification reaction of 1,6-hexamethylenediamine (HDA) with methyl carbamate (MC), ethyl carbamate (EC), and butyl car-bamate (BC) to afford dialkyl hexamethylene-1,6-dicarbamate (AHDC). By applying the optimized condi-tion, 100% conversion of HDA and 93% yield to diethyl hexamethylene-1,6-dicarbamate (EHDC) could be obtained using FeCl3 as catalyst. The desired products could be precipitated by adding water into the resulting mixture, and the activity of recovered catalyst could be maintained. |
| 学科主题 | 物理化学 |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2012-12-01 |
| 源URL | [http://210.77.64.217/handle/362003/2296]  |
| 专题 | 兰州化学物理研究所_绿色化学研究发展中心 兰州化学物理研究所_OSSO国家重点实验室 |
| 通讯作者 | Deng YQ(邓友全); Deng YQ(邓友全) |
| 推荐引用方式 GB/T 7714 | Deng YQ,Shang JP,Ma XY,et al. Synthesis of dialkyl hexamethylene-1,6-dicarbamate from 1,6-hexamethylenediamine and alkyl carbamate over FeCl3 as catalyst[J]. Catalysis Communications,2009,10:1248-1251. |
| APA | 邓友全,尚建鹏,马祥元,崔新江,石峰,&邓友全.(2009).Synthesis of dialkyl hexamethylene-1,6-dicarbamate from 1,6-hexamethylenediamine and alkyl carbamate over FeCl3 as catalyst.Catalysis Communications,10,1248-1251. |
| MLA | 邓友全,et al."Synthesis of dialkyl hexamethylene-1,6-dicarbamate from 1,6-hexamethylenediamine and alkyl carbamate over FeCl3 as catalyst".Catalysis Communications 10(2009):1248-1251. |
入库方式： OAI收割
来源：兰州化学物理研究所
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